Reakcije bakrovega(II) kinaldinata z izbranimi piperazini

Marc, Živana (avtor), Modec, Barbara (mentor)

Narejene so bile reakcije med bakrovim(II) kinaldinatom in piperazini: 1-metilpiperazinom, 1-etilpiperazinom, 1-(2-hidroksietil)piperazinom in samim piperazinom. Reakcije so potekale pri naslednjih pogojih: v avtoklavu pri 105 °C ali pa pri sobni temperaturi. V slednjem primeru smo reakcijsko zmes mešali z magnetnim mešalom. Pri reakciji z 1-metilpiperazinom je nastala koordinacijska spojina [Cu(quin)2(1-Mepz)2], pri reakciji z 1-etilpiperazinom pa [Cu(quin)2(1-Etpz)2]·1/2CH3CN. Pri reakcijah z 1-(2-hidroksietil)piperazinom koordinacijskih spojin s tem ligandom nismo izolirali. Produkt reakcije s piperazinom v avtoklavu najverjetneje vsebuje koordiniran piperazin in kinaldinat, reakcija pri sobni temperaturi da podoben produkt, vendar ta ni čist.

• Jezik: Slovenski jezik
• Ključne besede: koordinacijska kemija, baker(II), 1-metilpiperazin, 1-etilpiperazin, piperazin, 1-(2-hidroksietil)piperazin
• Vrsta gradiva: Diplomsko delo/naloga
• Tipologija: 2.11 - Diplomsko delo
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Leto izida: 2022
• PID: 20.500.12556/RUL-141878
• COBISS.SI-ID: 132914947
• Datum objave v RUL: 10.10.2022

MARC, Živana, 2022, Reakcije bakrovega(II) kinaldinata z izbranimi piperazini [na spletu]. Diplomsko delo. [Dostopano 19 maj 2025]. Pridobljeno s: https://repozitorij.uni-lj.si/IzpisGradiva.php?lang=slv&id=141878

Sekundarni jezik

• Jezik: Angleški jezik
• Naslov: Reactions of copper(II) quinaldinate with selected piperazines

Izvleček

Reactions of copper(II) quinaldinate with piperazines were performed. The used piperazines were 1-methylpiperazine, 1-ethylpiperazine, 1-(2-hydroxyethyl)piperazine and piperazine. Reactions were carried out in autoclaves at 105 °C or at ambient conditions. In the latter case, the mixtures were mixed throughout the whole reaction time. The 1-methylpiperazine reactions afforded [Cu(quin)2(1-Mepz)2], whereas the 1-ethylpiperazine reactions led to [Cu(quin)2(1-Etpz)2]·1/2CH3CN. The 1-(2-hydroxyethyl)piperazine reaction mixtures did not afford complexes with this ligand. The autoclave reaction with piperazine produced a compound that most likely contained both the quinaldinate and piperazine, whereas at ambient conditions similar product was obtained but not in a pure form

• Ključne besede: coordination chemistry, copper(II), 1-methylpiperazine, 1-ethylpiperazine, piperazine, 1-(2-hydroxyethyl)piperazine