500+ FACs Perovskite Solar Cells under Long-Term Stability Testing

Ajdič, Žan (avtor), Solorio, Fernando (avtor), Remec, Marko (avtor), Kikelj, Miha (avtor), Ali, Arslan (avtor), Glažar, Boštjan (avtor), Matič, Gašper (avtor), Brecl, Kristijan (avtor), Jankovec, Marko (avtor), Topič, Marko (avtor), Jošt, Marko (avtor)

The long-term stability of more than 500 FACs perovskite solar cells has been systematically investigated under various conditions. We first analyze resilience to moisture and show that with the 30 nm Al2O3 capping, we can perform long-term tests in air and eliminate moisture-related degradation. In the long-term MPP tracking tests, we then confirm that light is the driving degradation contributor by performing cyclic tests and testing under different light intensities. Visual changes of the perovskite absorber during the testing and spatial and spectral photoluminescence measurements reveal that phase segregation and the perovskite/C60 interface are the main culprits for degradation, while the perovskite degrades faster in electrically inactive areas. We thus show that by removing bromide ions from the FACs composition, cell stability, evaluated by the t80 lifetime, can improve 5-fold in the best case and that there is a linear correlation between t80 time and bias voltage during stability tracking. By testing a large number of samples (>500), we show with statistical relevance that long-term stability measurements show significantly higher spread (both batch-to-batch and intrabatch) than J–V measurements.

• Jezik: Angleški jezik
• Ključne besede: perovskite solar cells, long-term stability, maximum power point tracking, moisture and light degradation, voltage bias degradation, photoluminescence
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FE - Fakulteta za elektrotehniko
• Različica publikacije: Objavljena publikacija
• Leto izida: 2026
• Št. strani: Str. 3946–3955
• Številčenje: Vol. 18, issue 2
• PID: 20.500.12556/RUL-179444
• UDK: 621.383.51:549.641
• ISSN pri članku: 1944-8252
• DOI: 10.1021/acsami.5c24756
• COBISS.SI-ID: 268429571
• Datum objave v RUL: 13.02.2026

Gradivo je del revije

• Naslov: ACS applied materials & interfaces
• Skrajšan naslov: ACS appl. mater. interfaces
• Založnik: American Chemical Society
• ISSN: 1944-8252
• COBISS.SI-ID: 516049433

Licence

• Licenca: CC BY 4.0, Creative Commons Priznanje avtorstva 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by/4.0/deed.sl
• Opis: To je standardna licenca Creative Commons, ki daje uporabnikom največ možnosti za nadaljnjo uporabo dela, pri čemer morajo navesti avtorja.

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: perovskitne sončne celice, dolgoročna stabilnost, sledenje točki maksimalne moči, degradacija zaradi vlage in svetlobe, degradacija zaradi napetosti, fotoluminiscenca

Projekti

• Financer: ARIS - Javna agencija za znanstvenoraziskovalno in inovacijsko dejavnost Republike Slovenije
• Številka projekta: P2-0415
• Naslov: Fotovoltaika in elektronika

• Financer: ARIS - Javna agencija za znanstvenoraziskovalno in inovacijsko dejavnost Republike Slovenije
• Številka projekta: GC-0003
• Naslov: Nanostrukturirani hibridni polprevodniški materiali in naprave