Sinteza organorodijevih(III) kompleksov s 4-heteroaril-2-(metiltio)pirimidini

Jefim, Aleksander (avtor), Kljun, Jakob (mentor)

V okviru diplomske naloge sem poizkusil sintetizirati šest organorodijevih(III) kompleksov z izhodnim reaktantom diklorido(pentametilciklopentadienil)rodijevim(III) dimerom in serijo ligandov 4-heteroaril-2-(metiltio)pirimidinov. Dva od teh ligandov sta bila tudi pripravljena v okviru te diplomske naloge. Trije od šestih kompleksov so bili uspešno sintetizirani in okarakterizirani z NMR, IR in UV-Vis spektroskopijo ter masno spektrometrijo.

• Jezik: Slovenski jezik
• Ključne besede: rodij(III), pirimidin, kompleks, ligand, sinteza
• Vrsta gradiva: Diplomsko delo/naloga
• Tipologija: 2.11 - Diplomsko delo
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Leto izida: 2025
• PID: 20.500.12556/RUL-173074
• COBISS.SI-ID: 257644035
• Datum objave v RUL: 12.09.2025

Sekundarni jezik

• Jezik: Angleški jezik
• Naslov: Synthesis of organorhodium(III) complexes with 4-heteroaryl-2-(methylthio)pyrimidines

Izvleček

As part of my diploma thesis, I tried to synthesize six organorhodium(III) complexes with the starting reactant dichloride(pentamethylcyclopentadienyl)rhodium(III) dimer and a series of 4-heteroaryl-2-(methylthio)pyrimidine ligands. Two of these ligands were also prepared as part of this thesis. Three of the six complexes were successfully synthesized and characterized by NMR, IR and UV-Vis spectroscopy and mass spectrometry.

• Ključne besede: rhodium(III), pyrimidine, complex, ligand, synthesis