Tetrahydrated bis(monoaqua-bis(ethylenediamine)copper(II))-diaqua-bis(ethylenediamine)copper(II) dicitrate : preparation, crystal structure, Raman and FTIR spectra and paramagnetic behavior

Vakulka, Andrii (avtor), Goreshnik, Evgeny A. (avtor), Jagodič, Marko (avtor), Jagličić, Zvonko (avtor), Trontelj, Zvonko (avtor)

The crystals of the first copper(II) ethylenediamine complex containing citrate anion have been prepared and characterized. Despite the archetypical character of the copper(II) ethylenediamine complexes, some structural peculiarities were found to be interesting since they are quite rare even among the mentioned type of the complex compounds i.e. a presence of both mono and diaqua-bis(ethylenediamine)copper(II) cations together in the same crystal structure, intramolecular hydrogen bonding of the citric anion, cis,trans-configuration of the citric anion and the disordered C-C bond of the ethylenediamine molecule in the monoaquabis(ethylenediamine)copper(II) cation, which in fact is a co-existence of two energetically close dd and dk conformers. The Raman as well as FTIR spectra were recorded and discussed. Finally, the magnetic measurements have shown paramagnetic behavior of the prepared complex in a wide range of temperatures.

• Jezik: Angleški jezik
• Ključne besede: copper(II) complex, ethylenediamine complex, copper(II) citrate, crystal structure, Raman spectrum, FTIR spectrum
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FS - Fakulteta za strojništvo ; FGG - Fakulteta za gradbeništvo in geodezijo
• Status publikacije: Objavljeno
• Različica publikacije: Objavljena publikacija
• Leto izida: 2022
• Št. strani: Str. 2062-2076
• Številčenje: Vol. 75, no. 15/16
• PID: 20.500.12556/RUL-143691
• UDK: 548/549
• ISSN pri članku: 1029-0389
• DOI: 10.1080/00958972.2022.2126314
• COBISS.SI-ID: 123517699
• Datum objave v RUL: 09.01.2023

Gradivo je del revije

• Naslov: Journal of coordination chemistry
• Skrajšan naslov: J. coord. chem.
• Založnik: Taylor & Francis
• ISSN: 1029-0389
• COBISS.SI-ID: 515741465

Licence

• Licenca: CC BY-NC-ND 4.0, Creative Commons Priznanje avtorstva-Nekomercialno-Brez predelav 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by-nc-nd/4.0/deed.sl
• Opis: Najbolj omejujoča licenca Creative Commons. Uporabniki lahko prenesejo in delijo delo v nekomercialne namene in ga ne smejo uporabiti za nobene druge namene.

Projekti

• Financer: ARRS - Agencija za raziskovalno dejavnost Republike Slovenije
• Številka projekta: P1-0045
• Naslov: Anorganska kemija in tehnologija

• Financer: ARRS - Agencija za raziskovalno dejavnost Republike Slovenije
• Številka projekta: P2-0348
• Naslov: Nove slikovno-analitske metode