Sinteza rutenijevih koordinacijskih spojin s piritioni in trifenilarzinom

Košir, Ula (avtor), Turel, Iztok (mentor)

V diplomskem delu je predstavljena sinteza organorutenijevih koordinacijskih spojin, v katerih je na kovinski center poleg dvoveznega analoga piritiona, vezan še enovezni ligand trifenilarzin ali pa ligand pta. Najprej sem sintetizirala piritionske ligande, nato pa sem te ligande uporabila za sintezo koordinacijskih spojin. Komplekse sem očistila s kolonsko kromatografijo. Sintetizirane piritione sem karakterizirala z jedrsko magnetno resonanco (NMR), rutenijeve komplekse pa z jedrsko magnetno resonanco (NMR), infrardečo spektroskopijo (IR), UV-Vis spektroskopijo in masno spektroskopijo.

• Jezik: Slovenski jezik
• Ključne besede: pirition, trifenilarzin, pta, rutenij
• Vrsta gradiva: Diplomsko delo/naloga
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Leto izida: 2024
• PID: 20.500.12556/RUL-160888
• Datum objave v RUL: 05.09.2024

Sekundarni jezik

• Jezik: Angleški jezik
• Naslov: Synthesis of ruthenium coordination compounds with pyrithiones and triphenylarsine

Izvleček

The thesis presents the synthesis of organoruthenium coordination compounds, in which, in addition to the bidentately bonded pyrthionic analogue, a monodentate ligand triphenylarsine or pta is attached to the metal center. First, pyrithione ligands were synthesized, then these ligands were used to prepare the coordination compounds. The complexes were purified by column chromatography. The synthesized pyrithiones were characterized by nuclear magnetic resonance (NMR), and the ruthenium complexes were characterized by nuclear magnetic resonance (NMR), infrared spectroscopy (IR), UV-Vis spectroscopy and mass spectroscopy.

• Ključne besede: pyrithione, triphenylarsine, pta, ruthenium