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Insight into details of chemical exchange kinetics studied by NMR CPMG method
ID
Stepišnik, Janez
(
Author
),
ID
Mohorič, Aleš
(
Author
)
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https://link.springer.com/article/10.1007/s00723-024-01679-3
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Abstract
A more detailed insight into the chemical kinetics and dynamics of chemical exchanges within a molecule or between molecules in liquids is made possible by the NMR CPMG method, which, in addition to the exchange rate, gives its power spectrum, which contains information about the underlying processes of chemical exchange. The applicability of the method is demonstrated by measuring the chemical exchange in an aqueous solutions of sucrose, whose rate spectra have shapes that cannot be explained as transitions in a double potential well, but after interpretation using the chemical Langevin equations, it can be explained as a cascading chemical transition across several intermediate potential walls.
Language:
English
Keywords:
nuclear magnetic resonance
,
chemical kinetics
,
chemical exchanges
Work type:
Article
Typology:
1.01 - Original Scientific Article
Organization:
FMF - Faculty of Mathematics and Physics
Publication status:
Published
Publication version:
Version of Record
Year:
2024
Number of pages:
Str. 847–854
Numbering:
Vol. 55, iss. 8
PID:
20.500.12556/RUL-160339
UDC:
537.635
ISSN on article:
0937-9347
DOI:
10.1007/s00723-024-01679-3
COBISS.SI-ID:
202786051
Publication date in RUL:
26.08.2024
Views:
76
Downloads:
26
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Record is a part of a journal
Title:
Applied magnetic resonance
Shortened title:
Appl. magn. reson.
Publisher:
Springer Nature
ISSN:
0937-9347
COBISS.SI-ID:
14849029
Licences
License:
CC BY 4.0, Creative Commons Attribution 4.0 International
Link:
http://creativecommons.org/licenses/by/4.0/
Description:
This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Secondary language
Language:
Slovenian
Keywords:
jedrska magnetna resonanca
Projects
Funder:
ARIS - Slovenian Research and Innovation Agency
Project number:
P1-0060
Name:
Eksperimentalna biofizika kompleksnih sistemov in slikanje v biomedicini
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