20.500.12556/RUL-160339 Insight into details of chemical exchange kinetics studied by NMR CPMG method A more detailed insight into the chemical kinetics and dynamics of chemical exchanges within a molecule or between molecules in liquids is made possible by the NMR CPMG method, which, in addition to the exchange rate, gives its power spectrum, which contains information about the underlying processes of chemical exchange. The applicability of the method is demonstrated by measuring the chemical exchange in an aqueous solutions of sucrose, whose rate spectra have shapes that cannot be explained as transitions in a double potential well, but after interpretation using the chemical Langevin equations, it can be explained as a cascading chemical transition across several intermediate potential walls. nuclear magnetic resonance chemical kinetics chemical exchanges jedrska magnetna resonanca true false true Angleški jezik Slovenski jezik Članek v reviji 2024-08-26 13:31:42 2024-08-26 13:31:43 2024-08-27 03:52:26 0000-00-00 00:00:00 2024 0 0 Str. 847–854 iss. 8 Vol. 55 2024 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 537.635 0937-9347 10.1007/s00723-024-01679-3 202786051 s00723-024-01679-3.pdf s00723-024-01679-3.pdf 1 678DF1A8AB4A5B8B75DA31F23CF20B70 a9d444018f002d72aa6dbadc1f09fb983aaa28f95e1398ab5895ce280438091c 8b76c433-639f-11ef-8f74-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=188947 https://link.springer.com/article/10.1007/s00723-024-01679-3 0 b6d0b380-639e-11ef-8f74-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=188946 Fakulteta za matematiko in fiziko 0 0 0