Magnetic polydomain liquid crystal elastomers – synthesis and characterisation

Cmok, Luka (avtor), Vilfan, Mojca (avtor), Gyergyek, Sašo (avtor), Čopič, Martin (avtor)

Although liquid crystal elastomers (LCE) are a fascinating class of materials with interesting thermomechanical properties of their own, the aim is to enhance their performance or add new features, e.g. response to external stimuli. The generally weak response of organic materials can be significantly intensified by mixing nano-sized magnetic particles into the host polymer matrix. An alternative approach is chemically coupling the nanoparticles to the elastomer. We achieved this by bonding functionalised magnetic nanoplatelets to the backbone of a main-chain LCE and obtained polydomain magnetic liquid crystal elastomers. We measured the magnetisation curves in samples, which were exposed to either small or large magnetic fields – their response being a consequence of partial particle reorientation or magnetic moment flipping. In contrast to the samples, which were exposed to small magnetic field and in which the remanent magnetisation can be reset to zero by heating the sample, the samples with flipped magnetisation within the platelets cannot be reversed into the original state. Coupling of magnetic and mechanical properties shows a slight magneto-elastic response at elevated temperatures and a significant inverse magneto-elastic effect: the magnetisation caused by mechanical stretching is almost equal to the magnetisation caused by an external magnetic field.

• Jezik: Angleški jezik
• Ključne besede: elastomers, magnetic elastomers, ferromagnetic materials, hysteresis, magneto-elastic effect
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FMF - Fakulteta za matematiko in fiziko
• Status publikacije: Objavljeno
• Različica publikacije: Objavljena publikacija
• Leto izida: 2021
• Št. strani: Str. 1815-1826
• Številčenje: Vol. 48, no. 13
• PID: 20.500.12556/RUL-141240
• UDK: 53
• ISSN pri članku: 0267-8292
• DOI: 10.1080/02678292.2021.1901149
• COBISS.SI-ID: 57620995
• Datum objave v RUL: 26.09.2022

Gradivo je del revije

• Naslov: Liquid crystals
• Skrajšan naslov: Liq. cryst.
• Založnik: Taylor & Francis
• ISSN: 0267-8292
• COBISS.SI-ID: 1690628

Licence

• Licenca: CC BY-NC-ND 4.0, Creative Commons Priznanje avtorstva-Nekomercialno-Brez predelav 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by-nc-nd/4.0/deed.sl
• Opis: Najbolj omejujoča licenca Creative Commons. Uporabniki lahko prenesejo in delijo delo v nekomercialne namene in ga ne smejo uporabiti za nobene druge namene.