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Sinteza vinil substituiranih azometin iminskih derivatov in njihove fotokemične pretvorbe
ID Škrinjar, Martin (Author), ID Štefane, Bogdan (Mentor) More about this mentor... This link opens in a new window

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Abstract
Ena izmed pomembnih reakcij v klik kemiji je 1,3-dipolarna cikloadicija, ki spada med periciklične reakcije. Cikloadicija se uporablja za sintezo heterocikličnih sistemov z lihim številom atomov v obroču. V uvodu diplomskega dela se bom posvetil lastnostim in sintezi azometin iminov in pirazolidin-3-onom, ki lahko služijo kot izhodne spojine za pripravo najrazličnejših heterociklov, med katerimi bom več pozornosti namenil pirazolo[1,2-a]pirazolom. Eksperimentalni del diplomskega dela vključuje sintezo azometin iminov iz pirazolidin-3-onov in 1,3-dipolarno cikloadicijo azometin iminov na terminalne alkine za sintezo pirazolo[1,2-a]pirazolov ter njihove fotokemične pretvorbe.

Language:Slovenian
Keywords:1, 3-dipolarna cikloadicija, azometin imini, pirazolo[1, 2-a]pirazoli, fotoreakcije
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2022
PID:20.500.12556/RUL-139094 This link opens in a new window
COBISS.SI-ID:122243587 This link opens in a new window
Publication date in RUL:30.08.2022
Views:477
Downloads:132
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Secondary language

Language:English
Title:Synthesis of vinyl-substituted azomethine imine derivatives and their photochemical transformations
Abstract:
One of the most important reactions in click chemistry is 1,3-dipolar cycloaddition, which belongs to the pericyclic reactions. Cycloaddition is used to synthesise heterocyclic systems with an odd number of atoms in the ring. In the introduction of my work, I will focus on the properties and synthesis of azomethine imines and pyrazolidin-3-ones, which can serve as starting compounds for the preparation of a variety of heterocycles, paying more attention to pyrazolo[1,2-a]pyrazoles. The experimental part of the work includes the synthesis of azomethine imines from pyrazolidin-3-ones and 1,3-dipolar cycloaddition of azomethine imines to terminal alkynes for the synthesis of pyrazolo[1,2-a]pyrazoles and their photochemical transformations.

Keywords:1, 3-dipolar cycloaddition, azomethine imines, pyrazolo[1, 2-a]pyrazoles, photoreactions

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