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Nekatere pretvorbe alilnih alkoholov
ID Šporar, Petra (Author), ID Jereb, Marjan (Mentor) More about this mentor... This link opens in a new window

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Abstract
V zadnjih desetletjih so kemiki vlagali veliko truda med drugim tudi v razvoj metod, s katerimi sintetiziramo številne produkte, med katerimi so tudi karbonilne spojine iz alilnih alkoholov. Značilne pretvorbe alilnih alkoholov so tudi semipinakolne premestitve, izomerizacije in alilno aminiranje. Na začetku diplomskega dela se bom osredotočila na semipinakolne premestitve alilnih alkoholov. Njihov razvoj je znatno napredoval zadnji dve desetletji in med drugimi so velik napredek dosegli na področju novih tandemskih reakcij, pretvorb v prisotnosti elektrofilov, radikalskih procesov in katalitskih enantioselektivnih transformacij. Široko raziskane so izomerizacije alilnih alkoholov v aldehide in ketone, ki so osnovne spojine v laboratoriju in industriji, zato sem tudi predstavila izomerizacije, katalizirane z različnimi kompleksi. Na koncu diplomskega dela sem se dotaknila še aminiranja alilnih alkoholov, saj so alilni amini pogosto prisotni v različnih biološko aktivnih spojinah.

Language:Slovenian
Keywords:alilni alkohol, semipinakolna premestitev, izomerizacije, aminiranje
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2021
PID:20.500.12556/RUL-129283 This link opens in a new window
COBISS.SI-ID:76739075 This link opens in a new window
Publication date in RUL:01.09.2021
Views:879
Downloads:96
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Secondary language

Language:English
Title:Some conversions of allylic alcohols
Abstract:
In the last decades chemists have put a lot of effort into developing methods which are used to synthetize different products, some of which are carbonyl compounds from allylic alcohols. Typical conversions from allylic alcohols are also semipinacol rearrangement, isomerisation and allylic amination. At the beginning of the thesis I focus on semipinacol rearrangement of allylic alcohols. Their development has advanced in the last two decades, therefore a great progress has been achieved in the field of tandem reactions, transformations in the presence of electrophiles, radical processes and catalytic enantioselective transformations. Isomerisation of allylic alcohols has also been widely researched and presents a transformation of allylic alcohols into aldehydes and ketones which are basic compounds in laboratories and industry, therefore I present isomerisation catalysed with different complexes. At the end of the thesis I put an emphasis on amination of allylic alcohols since allylic amines are all-present in different biological compounds.

Keywords:allylic alcohol, semipinacol rearrangement, isomerization, amination

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