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Aktivacija C-H vezi imidazolilbenzenskih derivatov pod pogoji katalize s kovinami prehoda
ID PIPP, MATIC ANTON (Author), ID Požgan, Franc (Mentor) More about this mentor... This link opens in a new window

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Abstract
Tekom diplomskega dela sem pregledal znanstvene članke na temo direktne C-H funkcionalizacije preko aktivacije C─H vezi v prisotnosti kovine prehoda kot katalizatorja. Opisal sem mehanizme direktne arilacije, alkilacije in alkenilacije z rutenijevimi, paladijevimi in katalizatorji 3d kovin prehoda. Prav tako sem predstavil lastnosti in sintezo heksaarilbenzenskih derivatov ter uporabo imidazolilne skupine kot liganda. Na koncu sem izpisal še načrt dela, ki bi ga izvajal v laboratoriju, če mi tega ne bi preprečila epidemija COVID-19.

Language:Slovenian
Keywords:kataliza s kovinami, heterocikli, direktno ariliranje, heksaarilbenzenski derivati, imidazol
Work type:Bachelor thesis/paper (mb11)
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2020
COBISS.SI-ID:30059011 This link opens in a new window
Publication date in RUL:10.09.2020
Views:336
Downloads:81
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Secondary language

Language:English
Title:Transition-metal-catalyzed activation of C-H bonds of imidazolylbenzene derivatives
Abstract:
In this work scientific articles and reviews about direct C-H functionalization via transition-metal-catalyzed activation of C─H bonds were examined. Mechanisms of direct arylation, alkylation and alkenylation with ruthenium, palladium and 3d transition metal catalysts were described. Also, topics of hexaarylbenzene derivatives and imidazolyl group as ligand were discussed. At the end, the plan of work, I was supposed to do in a laboratory if not for epidemic of COVID-19, was written about.

Keywords:metal catalysis, heterocycles, direct arylation, hexaarylbenzene derivatives, imidazole

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