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Sinteza izbranih propargil triazolijevih soli
ID Mukaetov, Blagoj (Author), ID Košmrlj, Janez (Mentor) More about this mentor... This link opens in a new window

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Abstract
V diplomski nalogi smo se ukvarjali s sintezo propargil triazolijevih soli. Za tvorbo triazola smo uporabili z bakrom katalizirano reakcijo cikloadicije med azidom in alkinom. Iz 1-trimetilsilil-1,4-pentadiina in diazidometana, ki smo ga tvorili in situ iz diklorometana, smo pripravili spojino z dvema triazolnima obročema. Reakcijo smo katalizirali s CuSO4 · 5H2O. Opisali smo večstopenjsko pretvorbo sintetiziranega produkta v prekurzor tetradentatnega NHC liganda s štirimi triazolnimi obroči.

Language:Slovenian
Keywords:triazol, triazolijeve soli, CuAAC
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2020
PID:20.500.12556/RUL-119656 This link opens in a new window
COBISS.SI-ID:30417923 This link opens in a new window
Publication date in RUL:10.09.2020
Views:1371
Downloads:147
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Secondary language

Language:English
Title:Synthesis of selected propargyl triazolium salts
Abstract:
In the thesis, we dealt with the synthesis of a propargyl triazole salts. For the formation of the triazole, we used a copper-catalyzed cycloaddition reaction between azide and alkyne. From 1-trimethylsilyl-1,4-pentadiyne and diazidomethane that was formed in situ from dichloromethane, we prepared a compound with two triazole rings. The reaction was catalyzed with CuSO4 · 5H2O. A multistep conversion of the synthesized product to a precursor of a tetradentate NHC ligand with four triazole rings was discussed.

Keywords:triazole, triazolium salt, CuAAC

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