Sinteza železovih in bakrovih koordinacijskih spojin tiohidroksamskih kislin

Rapuš, Uroš (author), Kljun, Jakob (mentor)

Namen diplomske naloge je bil pripraviti železove in bakrove koordinacijske spojine tiohidroksamskih kislin ter njihova karakterizacija. V okviru diplomske naloge sem sintetiziral in optimiziral sintezo dveh tiohidroksamskih kislin, ter pripravil komplekse tudi s tremi drugimi kislinami. Sintetizirane tiohidroksamske kisline sem okarakteriziral z jedrsko magnetno resonanco (NMR), masno spektrometrijo in IR spektroskopijo. Pripravljene koodinacijske spojine pa sem okarakteriziral z masno spektrometrijo, elementno analizo CHN, ter IR in UV-Vis spektroskopijo.

• Language: Slovenian
• Keywords: tiohidroksamska kislina, železo, baker
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2019
• PID: 20.500.12556/RUL-109557
• COBISS.SI-ID: 1538319555
• Publication date in RUL: 05.09.2019

Secondary language

• Language: English

Abstract

The purpose of my thesis was to prepare and characterize iron and copper coordination compounds of thiohydroxamic acids. Two thiohydroxamic acids were prepared and their synthesis protocols were optimized. Complexes of said acids and complexes with three other acids were prepared. The synthesized acids were characterized with nuclear magnetic resonance (NMR), mass spectrometry and IR spectroscopy. Prepared coordination compounds were characterized with mass spectrometry, elemental analysis CHN, IR and UV-Vis spectroscopy.

• Keywords: thiohydroxamic acid, iron, copper