Bakrove(II) koordinacijske spojine s kinaldinatom in alkoholamini

Trontelj, Primož (author), Modec, Barbara (mentor)

V diplomskem delu so opisane reakcije [Cu(kinal)2(MeOH)]•MeOH (kinal– = kinaldinat) z dietanolaminom (H2dea). Iz reakcijskih zmesi je na sobni temperaturi izkristalizirala enojedrna spojina cis [Cu(kinal)2(H2dea)]1/2H2dea. Pri 105 C pa je potekla deprotonacija liganda, izločeni kristali so imeli sestavo [Cu2(kinal)2(Hdea)2] (Hdea– je anionska oblika liganda). Produktov reakcij s pantenolom še nismo identificirali.

• Language: Slovenian
• Keywords: koordinacijske spojine bakra(II)
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: PEF - Faculty of Education
• Year: 2017
• PID: 20.500.12556/RUL-96639
• COBISS.SI-ID: 11760457
• Publication date in RUL: 11.10.2017

Secondary language

• Language: English
• Title: Copper(II) coordination compounds with quinaldinate and alcoholamines

Abstract

The presented work describes reactions of [Cu(kinal)2(MeOH)]•MeOH (kinal– = quinaldinate) with diethanolamine (H2dea). Reactions at room temperature afforded a mononuclear compound cis [Cu(kinal)2(H2dea)]1/2H2dea. At 105 C, deprotonation of diethanolamine took place and the composition of the crystalline product was [Cu2(kinal)2(Hdea)2] (Hdea– stands for the anionic form of the ligand). Products of the reactions with panthenol remain to be identified.

• Keywords: coordination compounds of copper(II)