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Izboljšanje elektrolize vode pri povišanem tlaku z laserskim strukturiranjem platinaste površine
ID Lazova, Milena (Author), ID Golobič, Iztok (Mentor) More about this mentor... This link opens in a new window, ID Može, Matic (Comentor)

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Abstract
Prekritost površine elektrode z vodikovimi mehurčki omejuje učinkovitost elektrolize vode, saj zmanjšuje aktivno površino za elektrokemijsko reakcijo. Lasersko strukturiranje površine omogoča nadzor nad omočljivostjo, hrapavostjo in aktivno površino elektrode ter tako predstavlja enega od pristopov za izboljšanje učinkovitosti. V nalogi je bila zasnovana matrika eksperimentov ter izvedena primerjava gladke in lasersko strukturirane platinaste elektrode pri napetostih 3,0, 4,0 in 6,0 V ter tlakih 0, 0,5, 1 in 2 bar. Gostota električnega toka je bila izmerjena za obe vrsti elektrode, dinamika nastajanja in odcepljanja vodikovih mehurčkov pa dokumentirana s hitrotekočo kamero ter ovrednotena glede premera in frekvence odcepljanja. Rezultati kažejo, da lasersko strukturirana elektroda dosega višjo gostoto električnega toka kot gladka elektroda pri vseh obravnavanih napetostih, medtem ko je vpliv strukturiranja na velikost in frekvenco odcepljanja mehurčkov odvisen od napetosti in tlaka. Rezultati so bili kritično primerjani z ugotovitvami iz literature ter ovrednoteni glede prednosti in omejitev uporabe lasersko strukturiranih elektrod pri elektrolizi vode pod povišanim tlakom.

Language:Slovenian
Keywords:elektroliza vode, lasersko strukturiranje površine, platinasta mikroelektroda, tlak, dinamika mehurčkov, gostota električnega toka
Work type:Bachelor thesis/paper
Organization:FS - Faculty of Mechanical Engineering
Year:2026
PID:20.500.12556/RUL-186776 This link opens in a new window
Publication date in RUL:05.09.2026
Views:63
Downloads:21
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Secondary language

Language:English
Title:Enhancement of water electrolysis at elevated pressure using platinum surface laser texturing
Abstract:
The coverage of the electrode surface with hydrogen bubbles limits the efficiency of water electrolysis, as it reduces the active surface area available for the electrochemical reaction. Laser surface texturing enables control over wettability, roughness, and the active surface area of the electrode, and thus represents one of the approaches for improving efficiency. In this thesis, an experimental matrix was designed and a comparison was carried out between a smooth and a laser-textured platinum electrode at voltages of 3.0, 4.0, and 6.0 V and pressures of 0, 0.5, 1, and 2 bar. The current density was measured for both types of electrode, while the dynamics of hydrogen bubble formation and detachment were documented using a high-speed camera and evaluated in terms of bubble diameter and detachment frequency. The results show that the laser-textured electrode achieves a higher current density than the smooth electrode at atmospheric pressure across all examined voltages, whereas the effect of texturing on bubble size and detachment frequency depends on both voltage and pressure. The results were critically compared with findings from the literature and evaluated in terms of the advantages and limitations of using laser-textured electrodes in water electrolysis under elevated pressure.

Keywords:water electrolysis, laser surface texturing, platinum microelectrode, pressure, bubble dynamics, current density

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