Sinteza in pretvorbe 2,5-diamino-3,6-dikloro-1,4-benzokinona

Zupan, Jonatan (author), Svete, Jurij (mentor)

V diplomskem delu sem preizkusil sintezo 2,5-diamino-3,6-dikloro-1,4-benzokinona iz kloranila ter raziskal vpliv različnih topil na to pretvorbo. Z različnimi postopki izolacije in čiščenja sem poskušal izboljšati izkoristek reakcije. Pripravljeni 2,5-diamino-3,6 dikloro-1,4-benzokinon sem uporabil za preizkus različnih postopkov sinteze poli(tetraamino-1,4-benzokinona), ki potekajo pri blažjih pogojih kot znane sinteze. Produkte sem analiziral in okarakteriziral ter s tem potrdil nastanek želenih produktov.

• Language: Slovenian
• Keywords: organska sinteza, polikinoni, redoks aktivnost, organske elektrode, baterije
• Work type: Bachelor thesis/paper
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2026
• PID: 20.500.12556/RUL-185878
• Publication date in RUL: 21.08.2026

Secondary language

• Language: English
• Title: Synthesis and transformations of 2,5-diamino-3,6-dichloro-1,4-benzoquinone

Abstract

This thesis examines the synthesis of 2,5-diamino-3,6-dichloro-1,4-benzoquinone from chloranil and the influence of different solvents on this transformation. Several isolation and purification procedures were evaluated to improve the reaction yield. The resulting 2,5-diamino-3,6-dichloro-1,4-benzoquinone was then used to explore routes towards poly(tetraamino-1,4-benzoquinone) under milder conditions than those previously reported. The products were characterised using the available analytical methods, and their formation and composition were evaluated.

• Keywords: organic synthesis, poliquinons, redox activity, organic electrodes, batteries