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Induktivno testiranje visokoentropijskih zlitin
ID Robida, Janja (Author), ID Likozar, Blaž (Mentor) More about this mentor... This link opens in a new window, ID Plazl, Igor (Comentor)

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Abstract
Etilen oksid je pomembna surovina, ki se uporablja v mnogih industrijskih procesih. Je brezbarven lahko hlapen plin z značilnim sladkim vonjem in visoko reaktivnostjo. Predstavlja glavno surovino za proizvodnjo številnih kemikalij, predvsem etilen glikola. Tradicionalna proizvodnja etilen oksida poteka z neposredno oksidacijo etilena s kisikom ob pristnosti ustreznega katalizatorja. Kot najustreznejši se je zaenkrat izkazal srebrov katalizator. Za dosego željene konverzije in selektivnosti mora reakcija potekati pri povišani temperaturi in tlaku. Zaradi želje po optimizaciji konvencionalne proizvodnje se je pričela razvijati epoksidacija etilena s kisikom z indukcijsko katalizo. To je metoda, pri kateri se katalizator prične segrevati ob izpostavljenosti izmeničnemu elektromagnetnemu polju. Takšna tehnika omogoča izjemno hitro, homogeno in kontrolirano segrevanje katalizatorja, kar izboljša reakcijske pogoje in privede do boljših rezultatov. Za uspešno izvajanje indukcijske katalize potrebujemo katalizator, ki se odziva na zunanje magnetno polje. Za učinkovito delovanje pa katalizator potrebuje še katalitske delce, med katere sodijo tudi visoko entropijske zlitine. To so zlitine, ki vsebujejo več osnovnih elementov v približno enakih molskih deležih. Takšna sestava izboljšuje določene lastnosti materiala, zaradi česar so te zlitine primerne za indukcijsko katalizo. Za oceno primernosti katalizatorjev z visokoentropijskimi zlitinami za epoksidacijo etilena s kisikom z indukcijsko katalizo, sem sintetizirala različne katalizatorje z visokoentropijskimi zlitinami in brez njih. Sintetizirane katalizatorje sem testirala v indukcijskem reaktorju pri različnih reakcijskih pogojih. Dobljeni produkti reakcije kažejo na to, da katalizatorji z visokoentropijskimi zlitinami lahko dosežejo primerljive rezultate kot referenčni katalizatorji brez visokoentropijskih zlitin. Dobljene reakcijske rezultate sem dodatno potrdila s pomočjo karakterizacijskih tehnik, kot so magnetometrija vibrirajočih vzorcev (VSM), Brunauer-Emmett-Teller metoda (BET), rentgenska difrakcijska analiza (XRD) in vrstična presevna elektronska mikroskopija (STEM).

Language:Slovenian
Keywords:etilen oksid, visokoentropijske zlitine, indukcijska kataliza
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2026
PID:20.500.12556/RUL-183555 This link opens in a new window
COBISS.SI-ID:283946755 This link opens in a new window
Publication date in RUL:15.06.2026
Views:79
Downloads:56
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Secondary language

Language:English
Title:Inductive testing of high-entropy alloys
Abstract:
Ethylene oxide is an important raw material used in many industrial processes. It is colorless, volatile gas with a characteristic sweet odor and high reactivity. It is the main raw material for the production of many chemicals, especially ethylene glycol. Traditional ethylene oxide production involves the direct oxidation of ethylene with oxygen in the presence of a suitable catalyst. Silver catalyst has proven to be the most suitable for this purpose. To achieve the desired conversion and selectivity, the reaction must take place at elevated temperature and pressure. To optimize conventional production, the development of ethylene epoxidation with oxygen using induction catalysis began. This method uses a catalyst that heats up when exposed to an alternating electromagnetic field. This technique enables extremely fast, homogeneous and controlled heating of the catalyst, improving reaction conditions and leading to better results. For successful induction catalysis, a catalyst that responds to an external magnetic field is required. However, effective operation also depends on catalytic particles, which include high-entropy alloys. These alloys contain several base elements in approximately equal molar rations. This composition enhances certain properties of the material, making them suitable for induction catalysis. To determine whether catalysts with high-entropy alloys are suitable for the epoxidation of ethylene with oxygen using induction catalysis, I synthesized various catalysts with and without high-entropy alloys. I tested the synthesized catalysts in an induction reactor under various conditions. The reaction products obtained show that catalysts with high-entropy alloys achieved comparable results to reference catalysts without high-entropy alloys. I confirmed the reaction results using characterization techniques, such as vibrating sample magnetometry (VSM), Brunauer-Emmett-Teller analysis (BET), X-ray diffraction (XRD) and scanning transmission electron microscopy (STEM).

Keywords:ethylene oxide, high-entropy alloys, induction catalysis

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