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Imobilizacija fotokatalizatorja na različne nosilce za odstranjevanje farmacevtskih učinkovin in PFOA iz vode
ID Rifelj, Petra (Author), ID Lavrenčič Štangar, Urška (Mentor) More about this mentor... This link opens in a new window

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Abstract
V diplomskem delu sem preučevala imobilizacijo dopiranega TiO$_2$ na različne nosilce ter njegovo učinkovitost pri razgradnji izbranih farmacevtskih učinkovin in PFOA v vodi. Cilj je bil pripraviti stabilne plasti katalizatorja, ki dobro delujejo v vodnem okolju in jih je mogoče večkrat uporabiti. Za najbolj primeren nosilec se je izkazala hrapava PET plastika, saj so bile plasti na njej enakomerne in stabilne, kar je potrdila tudi FTIR analiza. Steklo se je obneslo slabše, predvsem zaradi slabšega oprijema katalizatorja. Pri poskusih razgradnje so se bolje razgrajevale bolj hidrofobne farmacevtske spojine, medtem ko sta sulfametoksazol in fenitoin ostala skoraj nespremenjena. Pri PFOA sem najprej opazila adsorpcijo na PET, nato pa počasno fotokatalitsko razgradnjo, ki sicer ni bila popolna, vendar nakazuje potencial za nadaljnji razvoj sistema. Rezultati kažejo, da imobilizirani TiO$_2$ na PET plastiki predstavlja obetaven pristop za fotokatalitsko čiščenje vode, predvsem zaradi stabilnosti plasti in dobre aktivnosti pri izbranih onesnaževalih.

Language:Slovenian
Keywords:katalizator, perfluorirane alkilne spojine, imobilizacija, TiO$_2$, farmacevtske učinkovine
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2026
PID:20.500.12556/RUL-182948 This link opens in a new window
COBISS.SI-ID:282180099 This link opens in a new window
Publication date in RUL:29.05.2026
Views:99
Downloads:65
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Secondary language

Language:English
Title:Immobilization of a photocatalyst on different supports for removing pharmaceuticals and PFOA from water
Abstract:
In this thesis, I examined the immobilization of doped TiO$_2$ on different supports and evaluated its efficiency in degrading selected pharmaceutical compounds and PFOA in water. The main goal was to prepare stable catalyst layers that perform well in aqueous environments and can be reused multiple times. The most suitable support proved to be rough PET plastic, as the catalyst formed uniform and stable layers on its surface, which was also confirmed by FTIR analysis. Glass performed less effectively, mainly due to the weaker adhesion of the catalyst. In the degradation experiments, more hydrophobic pharmaceuticals showed better degradation, while sulfamethoxazole and phenytoin remained almost unchanged. For PFOA, I first observed adsorption onto the PET surface, followed by slow photocatalytic degradation. Although complete degradation was not achieved, the results show clear potential for further improvement.

Keywords:catalyst, perfluorinated alkyl substances, immobilisation, TiO$_2$, pharmaceuticals

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