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Stabilnost vodnih suspenzij TiO$_2$ v prisotnosti nižjih alkoholov
ID Cerkovnik, Gaber (Author), ID Reščič, Jurij (Mentor) More about this mentor... This link opens in a new window

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Abstract
Nanodelci TiO$_2$ se uporabljajo v številnih tehnoloških procesih. Ker so netopni, je treba suspenzije stabilizirati in preprečiti njihovo agregacijo, ki vodi do izločanja nanodelcev. To smo poskušali doseči tako, da smo nanodelce suspendirali v mešanicah vode in alkoholov metanola, etanola in propan-2-ola. Poleg tega smo spreminjali pH, in sicer smo suspenzijam nastavili pH vrednosti 2, 7 in 10. Vpliv sestave medija in pH vrednosti na stabilnost suspenzij smo analizirali z merjenjem zeta potenciala in hidrodinamskega radija nanodelcev. Ugotovili smo, da je absolutna vrednost zeta potenciala nanodelcev TiO$_2$ najmanjša v prisotnosti propan-2-ola in največja v sistemih z metanolom. Agregati nanodelcev pa so največji tam, kjer je zeta potencial najmanjši.

Language:Slovenian
Keywords:titanov dioksid, koloidna kemija, zeta potencial, hidrodinamski radij
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-176684 This link opens in a new window
COBISS.SI-ID:264985347 This link opens in a new window
Publication date in RUL:09.12.2025
Views:397
Downloads:96
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Secondary language

Language:English
Title:stability of aqueous suspensions of TiO$_2$ in the presence of low alcohols
Abstract:
TiO$_2$ nanoparticles are used in numerous technological processes. Since they are insoluble, suspensions must be stabilized to prevent their aggregation, which leads to the separation of nanoparticles. We attempted to achieve this by suspending the nanoparticles in mixtures of water and methanol, ethanol, and propan-2-ol. In addition, we varied the pH by adjusting the suspensions to pH values of 2, 7, and 10. We analyzed the effect of the medium composition and pH value on the stability of the suspensions by measuring the zeta potential and the hydrodynamic radius of the nanoparticles. We found that the absolute value of the zeta potential of TiO$_2$ nanoparticles is lowest in the presence of propan-2-ol and highest in systems with methanol. Nanoparticle aggregates are largest where the zeta potential is lowest.

Keywords:titanium dioxide, colloid chemistry, zeta potential, hydrodynamic radius

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