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Raziskovanje termičnih lastnosti reciklirane plastike v primerjavi s primarnim materialom
ID Savkov, Aleksej (Author), ID Čelan Korošin, Nataša (Mentor) More about this mentor... This link opens in a new window

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Abstract
V diplomskem delu so bile raziskane termične lastnosti reciklirane PET plastike z metodo diferenčne dinamične kalorimetrije (DSC). Analizirani so bili trije vzorci različnih izvorov (zelena plastenka Radenska, brezbarvna plastenka Jar in črna posodica Crown), primerjalno pa tudi referenčna PET-folija. Izvedene so bile meritve pri večjih in manjših masah vzorcev ter s cikličnim in šok hlajenjem. Posebna pozornost je bila namenjena določanju steklastega prehoda (T$_g$), kristaliničnosti in vplivu mase na obliko krivulj. Rezultati kažejo, da imajo vzorci različnih izvorov različne stopnje kristaliničnosti, da se steklasti prehodi bolj izraziti pri manjših masah vzorcev ter da ponovljeno gretje omogoča zanesljivejšo oceno T$_g$. Ugotovitve prispevajo k boljšemu razumevanju lastnosti recikliranega PET in so uporabne pri ocenjevanju njegove ponovne uporabnosti.

Language:Slovenian
Keywords:PET, DSC, T$_g$, kristaliničnost, ciklična metoda, šok hlajenje
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-176573 This link opens in a new window
COBISS.SI-ID:259992579 This link opens in a new window
Publication date in RUL:04.12.2025
Views:413
Downloads:196
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Secondary language

Language:English
Title:Investigation of the thermal properties of recycled plastic compared to virgin material
Abstract:
In this thesis, the thermal properties of recycled PET plastic were analyzed using differential scanning calorimetry (DSC). Three samples of different origin were analyzed (a green Radenska bottle, a colorless Jar bottle, and a black Crown protein container), as well as a PET reference film for comparison. The measurements were performed with both larger and smaller sample masses, using cyclic and shock cooling methods. Particular attention was paid to the determination of the glass transition temperature (T$_g$), the crystallinity, and the influence of the sample mass on the shape of the DSC curves. The results show that samples from different sources have different degrees of crystallinity, that glass transitions are more pronounced with smaller sample masses, and that repeated heating allows a more reliable estimation of T$_g$. These results contribute to a better understanding of the properties of recycled PET and are useful for evaluating its potential for reuse.

Keywords:PET, DSC, T$_g$, crystallinity, cyclic method, shock cooling

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