Mechanical properties, microstructure, and tribological performance of coated polyether-ketone-ketone (PEKK) polymer

Al-Rjoub, Abbas (author), Yaqub, Talha Bin (author), Nadeem, Irfan (author), Cavaleiro, Albano (author), Kalin, Mitjan (author), Emami, Nazanin (author)

This study investigates the mechanical properties, microstructure, and tribological performance of CrN and CrAlN coatings. The coatings were deposited by low power DC reactive magnetron sputtering (PVD) on semicrystalline polyether-ketone-ketone (PEKK) substrates. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) confirmed PEKK's thermal stability, with a glass transition temperature of 158.0 °C and a melting point of 309.1 °C, ensuring compatibility with low-temperature coating processes. Microstructural analysis revealed dense, columnar coatings, with CrAlN exhibiting finer grains but minor interfacial voids/cracks that unaffected its adhesion. Tribological tests against stainless steel balls (SS) showed that CrN outperformed CrAlN, reducing the coefficient of friction (COF) by 39 % and specific wear volume by 78 % compared to uncoated PEKK, owing to its higher hardness and the formation of a protective Cr-oxides tribolayer. These results establish CrN as the superior coating for enhancing PEKK's durability and tribological performance, highlighting its potential for applications demanding high durability and wear resistance.

• Language: English
• Keywords: coated PEKK, friction, wear, coating adhesion
• Work type: Article
• Typology: 1.01 - Original Scientific Article
• Organization: FS - Faculty of Mechanical Engineering
• Publication status: Published
• Publication version: Version of Record
• Year: 2025
• Number of pages: 11 str.
• Numbering: Vol. 517, [article no.] 132872
• PID: 20.500.12556/RUL-175630
• UDC: 539.92
• ISSN on article: 1879-3347
• DOI: 10.1016/j.surfcoat.2025.132872
• COBISS.SI-ID: 256173571
• Publication date in RUL: 06.11.2025

Record is a part of a journal

• Title: Surface & coatings technology
• Publisher: Elsevier
• ISSN: 1879-3347
• COBISS.SI-ID: 23035397

Licences

• License: CC BY 4.0, Creative Commons Attribution 4.0 International
• Link: http://creativecommons.org/licenses/by/4.0/
• Description: This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

• Language: Slovenian
• Keywords: prevlečen PEKK, trenje, obraba, adhezija prevleke

Projects

• Funder: ARIS - Slovenian Research and Innovation Agency
• Project number: P2-0231
• Name: Tribologija

• Funder: ARRS - Slovenian Research Agency
• Funding programme: Slovenian Research and Innovation Agency
• Project number: MSCA-COFUND-5100-237
• Name: /