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Vpliv vrste in koncentracije fotoiniciatorjev na utrjevanje pigmentiranega premaza za les z UV LED tehnologijo
ID Pestotnik, Klara (Author), ID Petrič, Marko (Mentor) More about this mentor... This link opens in a new window

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Abstract
V okviru diplomske naloge smo raziskovali kateri fotoiniciatorji in v kakšnih deležih še zadovoljivo utrdijo premaz po izpostavitvi UV-LED viru svetlobe. Preizkušali smo sedem različnih fotoiniciatorjev s štirimi različnimi deleži, skupno smo imeli 28 različnih vzorcev. Vse vzorce, utrjene z UV-LED tehnologijo, smo ocenjevali po različnih vnaprej določenih merilih. Kot pričakovano so vzorci z višjim deležem fotoiniciatorja bolje utrdili kot tisti z manjšim deležem, prav tako se je pokazala razlika med posameznimi fotoiniciatorji. Fotoiniciatorji A, B, C, E in F so utrdili zadovoljivo, medtem ko fotoiniciatorja D in G nista primerna za utrjevanje kot samostojna fotoiniciatorja. Rezultate smo podkrepili tudi z analitskimi metodami, kjer smo s plinsko kromatografijo primerjali vzorec, utrjen z UV-LED tehnologijo, z vzorcem, utrjenim s klasično UV tehnologijo in dokazali, da je pri UV-LED utrjevanju potrebno uporabiti fotoiniciatorje, ki so primerni za UV-LED sijalko specifične valovne dolžine. Poleg dobrega utrjevanja so pri izbiri pravega fotoiniciatorja pomembne tudi druge lastnosti, kot so na primer cena, dostopnost na trgu, način vključitve v premaz in rumenenje takoj po utrjevanju. Rumenenje smo testirali na pet vzorcih: A50, C50, E50, F5 in F15, za primerjavo pa smo testirali tudi fotoiniciator, ki se ga uporablja v standardnih formulacijah UV utrjujočih premazov. Ugotovili smo, da je pri fotoiniciatorju F rumenenje preveliko in zato ni primeren za bele pigmentirane premaze.

Language:Slovenian
Keywords:les, premaz, fotoiniciator, UV utrjevanje, UV-LED utrjevanje
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:BF - Biotechnical Faculty
Publisher:[K. Pestotnik]
Year:2025
PID:20.500.12556/RUL-173379 This link opens in a new window
UDC:630*829
COBISS.SI-ID:249243907 This link opens in a new window
Publication date in RUL:17.09.2025
Views:549
Downloads:104
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Secondary language

Language:English
Title:Effects of photoinitiator type and concentration on the curing of pigmented wood coatings using UV-LED technology
Abstract:
As part of our diploma thesis, we investigated which photoinitiators and in what concentrations satisfactorily cure wood coatings after exposure to a UV-LED light source. We tested seven different photoinitiators with four different concentrations for a total of 28 different samples. All samples cured with UV-LED technology were evaluated according to various predefined criteria. As expected, the samples with a higher concentration of photoinitiator cured better than those with a lower concentration, and a difference between individual photoinitiators was also shown. Photoinitiators A, B, C, E and F cured satisfactorily, while photoinitiators D and G are not suitable for curing as independent photoinitiators. We also supported the results with analytic tools, where we compared the sample cured with UV-LED technology with the sample cured with classic UV technology using gas chromatography and proved that in UV-LED curing it is necessary to use photoinitiators which are suitable for UV-LED lamps of specific wavelengths. In addition to good curing, other properties are also important when choosing the right photoinitiator, such as price, market availability, method of incorporation into the coating and yellowing immediately after curing. We tested the yellowing on five samples: A50, C50, E50, F5 and F15, for comparison we also tested the photoinitiator used in standard formulations of UV-curable coatings. We found that the yellowing of photoinitiator F was too high, and therefore not suitable for white pigmented coatings.

Keywords:wood, coating, photoinitiator, UV curing, UV-LED curing

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