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Magnetne lastnosti preprostih bakrovih in kobaltovih spojin
ID Kmetič, Žan (Author), ID Kozlevčar, Bojan (Mentor) More about this mentor... This link opens in a new window

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Abstract
Uporabil sem nekaj preprostih bakrovih in kobaltovih spojin ter jim izmeril njihov magnetni odziv na magnetni tehtnici. Te spojine so: [Cu$_4$(OH)$_6$SO$_4$]$_n$ 1, [Cu$_2$(CH$_3$COO)$_4$(H$_2$O)$_2$] 2, [Cu$_2$(C$_5$H$_{11}$COO)$_4$]$_n$ 3, [Cu$_2$(C$_8$H$_{17}$COO)$_4$]$_n$ 4, [CuCl]$_n$ 5, [Co(CH$_3$COO)$_2$(H$_2$O)$_4$] 6, [Co(NH$_3$)$_6$](Cl)$_3$ 7 in Na$_3$[Co(NO$_2$)$_6$] 8. Nekatere spojine sem sintetiziral, nekatere so bile izolirane na študentskih laboratorijskih vajah, nekatere so bile komercialne. Z IR spektri sem spojine opazoval tudi po čistosti in vrstah kemijskih vezi, ki so prisotne. Formule teh spojin sem preveril tudi po znanih strukturnih opisih večine od teh spojin. Izračuni efektivnega magnetnega momenta teh spojin se skladajo z oksidacijskim števili za 1-4, ki vsebujejo Cu(II) ter imajo njihovo antiferomagnetno sklopitev. Po drugi strani sem v spojini 6 potrdil Co(II), v 7 in 8 pa Co(III) zvrsti. Kobaltove spojine potrjujejo, da so njihovi kovinski ioni magnetno izolirani. Barva in magnetni odziv bakrove spojine 5 nakazuje, da je prišlo do oksidacije vsaj dela vzorca iz Cu(I) v Cu(II).

Language:Slovenian
Keywords:baker, kobalt, magnetizem, struktura, IR
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-172629 This link opens in a new window
COBISS.SI-ID:255992835 This link opens in a new window
Publication date in RUL:10.09.2025
Views:147
Downloads:28
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Secondary language

Language:English
Title:Magnetic properties of simple copper and cobalt compounds
Abstract:
Several simple copper and cobalt compounds were measured for their magnetic susceptibility using a magnetic balance. These compounds were: [Cu$_4$(OH)$_6$SO$_4$]$_n$ 1, [Cu$_2$(CH$_3$COO)$_4$(H$_2$O)$_2$] 2, [Cu$_2$(C$_5$H$_{11}$COO)$_4$]$_n$ 3, [Cu$_2$(C$_8$H$_{17}$COO)$_4$]$_n$ 4, [CuCl]$_n$ 5, [Co(CH$_3$COO)$_2$(H$_2$O)$_4$] 6, [Co(NH$_3$)$_6$](Cl)$_3$ 7 and Na$_3$[Co(NO$_2$)$_6$] 8. Some of these compounds were syntesized, some were isolated in the student laboratory courses, and some were commercial. IR spectra were also measured to check the purity of these compounds and for the types of chemical bonds present. The formulae of these compounds were checked against the reported structural descriptions. Calculated effective magnetic moments are consistent with the oxydation states of 1-4 having Cu(II) and exhibit antiferromagnetic coupling. On the other hand, Co(II) was confirmed for 6, while compounds 7 and 8 contain Co(III) species. All cobalt compounds confirm that their metal ions are magnetically isolated. The color and magnetic susceptibility of copper compound 5 suggest that an oxidation took place with at least a part of the sample from Cu(I) to Cu(II).

Keywords:copper, cobalt, magnetism, structure, IR

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