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Sodobni pristopi proizvodnje vodikovega peroksida : inovativne metode in trajnostni vidiki
ID Lenarčič, Tomaž (Author), ID Plazl, Igor (Mentor) More about this mentor... This link opens in a new window

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Abstract
Vodikov peroksid je zelo pomemben oksidant, ki se uporablja na različnih področjih, zato se ga proizvede več kot štiri milijone ton na leto. Trenutno se ga večina proizvaja po antrakinonskem postopku, ki zaradi velike porabe energije in organskih topil močno onesnažuje okolje. Zaradi tega se posveča vse več pozornosti raziskovanju novih, okolju prijaznejših pristopov. Proizvodnja s fotokatalizo je eden od pristopov, kjer je vir energije sončna svetloba. Sevanje povzroči vzbujeno stanje polprevodnika ali molekule, kar privede do ločitve naboja in nato poteka redoks reakcij na površini katalizatorja. Njegova izbira je zelo pomembna, saj mora favorizirati reakcijske poti ORR ali WOR, kjer je končni produkt H$_2$O$_2$. Med bolj obetavnimi fotokatalizatorji so TiO$_2$, gC$_3$N$_4$ ter katalizatorji iz skupin COF, MOF in polimerov brez kovin. Naslednji pristop, ki je trenutno najbolj raziskan, je elektrokataliza. Elektrolitsko celico sestavljajo vir električne napetosti, elektrolita in anoda, kjer poteka oksidacija ter katoda, kjer poteka redukcija. Katalizatorji so v večini primerov že sestavni del elektrode, njihov namen pa je favoritizirati 2e$^−$-ORR ali 2e$^−$-WOR, ki sta najboljši poti za sintezo H$_2$O$_2$. Načinov za pripravo ustreznega katalizatorja je veliko, kot so dopiranje, inženiring napak, modifikacija kristalnih ravnin in inženirstvo medfaz. Poleg kovinskih oksidov, ki so pokazali dobro učinkovitost, postajajo vse bolj aktualni tudi katalizatorji na osnovi ogljika, ki so cenovno dostopnejši od žlahtnih kovin. Fotoelektrokemijski pristop združuje lastnosti fotokatalize in elektrokatalize. Sistem je lahko sestavljen iz fotoanode ali temne anode ter fotokatode ali temne katode, kjer fotocelica zniža potrebno prednapetost sistema in s tem zmanjša porabo električne energije med procesom. Za razliko od fotokatalize, ki v večini potrebuje žrtvene reagente za učinkovito delovanje in elektrokatalizo, ki vsebuje elektrolite, plazemska tehnologija zahteva le kisik, vodo in katalizator. Za proizvodnjo H$_2$O$_2$ se uporablja sistem plin-tekočina-trdna snov z iniciacijo plazemske razelektritve z mehurčki kisika v vodo, obdano s suspenzijo trdnega katalizatorja. Plazemska tehnologija je pokazala boljše rezultate od fotokatalize in elektrokatalize, zahteva pa veliko večje količine električne energije od ostalih pristopov.

Language:Slovenian
Keywords:vodikov peroksid, fotokataliza, elektrokataliza, fotoelektrokemija, plazemska tehnologija
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-172627 This link opens in a new window
COBISS.SI-ID:255927555 This link opens in a new window
Publication date in RUL:10.09.2025
Views:390
Downloads:121
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Secondary language

Language:English
Title:Modern approaches to hydrogen peroxide production : innovative methods and sustainable aspects
Abstract:
Hydrogen peroxide is a very important oxidizer used in various fields, which is why it is produced in more than four million tons per year. Currently, most of it is produced using the anthraquinone process, which significantly pollutes the environment due to its high energy consumption and use of organic solvents. Due to this, more attention is being paid to researching new, environmentally friendly production methods. Production with photocatalysis is one of the approaches where the energy source is sunlight. Radiation causes an excited state of the semiconductor or molecule, resulting in charge separation. Then, redox reactions occur on the surface of the catalyst. Its selection is very important, as he must favour the ORR or WOR reaction pathways, where the final product is H$_2$O$_2$. Among the more promising catalysts are TiO$_2$, gC$_3$N$_4$, and catalysts from the COF, MOF, and metal-free polymer groups. The following approach, which is currently the most extensively researched, is electrocatalysis. The electrolytic cell consists of a voltage source, electrolyte, and anode, where oxidation occurs, and cathode, where reduction occurs. Catalysts are in most cases already a part of the electrode, and their purpose is to favour 2e$^−$-ORR and 2e$^−$-WOR, which are the best pathways for H$_2$O$_2$ synthesis. There are many ways to prepare an appropriate catalyst, such as doping, defect engineering, facet engineering, and interface engineering. In addition to metal oxides, which have shown good efficiency, carbon-based catalysts are becoming increasingly popular, as they are more affordable than noble metals. Photoelectrochemical approach combines the properties of photocatalysis and electrocatalysis. The system can consist of a photoanode or a dark anode and a photocathode or a dark cathode, where the photocell reduces the bias and thus reduces the power consumption during the process. Unlike photocatalysis, which in most cases requires sacrificial reagents for effective operation, and electrocatalysis, which contains electrolytes, plasma technology requires only oxygen, water, and a catalyst. A gas-liquid-solid system with plasma discharge initiation with oxygen bubbles in water surrounded by a suspension of solid catalyst is used to produce H$_2$O$_2$. Plasma technology has shown better results than photocatalysis and electrocatalysis, but it requires much more electricity than other approaches.

Keywords:hydrogen peroxide, photocatalysis, electrocatalysis, photoelectrochemistry, plasma technology

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