Sinteza in karakterizacija srebrovih(I) kompleksov s kelatnimi 2-(metilitio)pirimidini

Stefanović, Natalija (author), Kljun, Jakob (mentor)

V sklopu diplomskega dela sem sintetizirala tri nove komplekse srebra(I) z izbranimi kelatnimi 2-metiltio-4-(heteroaril)pirimidini. V teh kompleksih je razmerje med ligandom in kovino 2:1, uporabljen pa je še heksafluorofosfatni ion kot protiion. Komplekse sem fizikalno-kemijsko karakterizirala z različnimi spektroskopskimi in analitskimi tehnikami ter tako nedvoumno potrdila njihovo zgradbo in čistost vzorcev.

• Language: Slovenian
• Keywords: srebro(I), koordinacijske spojine, substituirani pirimidini, sinteza
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2025
• PID: 20.500.12556/RUL-172553
• COBISS.SI-ID: 255276547
• Publication date in RUL: 08.09.2025

Secondary language

• Language: English
• Title: Synthesis and characterization of silver(I) complexes with chelating 2-(methylthio)pyrimidines

Abstract

As part of my thesis, I synthesized three new silver(I) complexes with selected chelated 2-methylthio-4-(heteroaryl)pyrimidines. In these complexes, the ligand-metal ratio is 2:1, and a hexafluorophosphate ion is used as an counterion. I characterized the complexes physicochemically using various spectroscopic and analytical techniques, thus unambiguously confirming their structure and purity of the samples.

• Keywords: silver(I), coordination compounds, substituted pyrimidines, synthesis