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Razvoj naprednih elektrokemijskih sistemov s turbostratičnim “Flash“ grafenom kot dodatkom za povečanje učinkovitosti Li-S akumulatorjev v etrskih elektrolitih
ID Šlosar, Tim (Author), ID Vižintin, Alen (Mentor) More about this mentor... This link opens in a new window, ID Genorio, Boštjan (Comentor)

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Abstract
Litij-žveplovi akumulatorji so zaradi visoke specifične teoretične energijske gostote ena izmed obetavnih možnosti za shranjevanje energije v prihodnosti. Vendar se v praksi srečujejo s kar nekaj izzivi, kot so slaba prevodnost žvepla, raztapljanje polisulfidov, formiranje dendritov na površini anode in nestabilnost katod. V okviru naloge smo primerjali delovanje dveh ogljikovih nosilcev – mezoporoznega ogljika ENSACO in turbostratičnega “flash” grafena (tFG) – v kompozitih z žveplom. Pripravljene vzorce smo analizirali z elektronsko vrstično mikroskopijo (SEM), termogravimetrično analizo (TGA), meritvijo stičnega kota za določanje omočljivosti, rentgensko fotoelektronsko spektroskopijo (XPS), ciklično voltametrijo (CV) ter z galvanostatskimi meritvami praznjenja in polnjenja pri različnih tokovnih hitrostih. Pomembno vlogo je igrala tudi uporaba in primerjava dveh različnih etrskih elektrolitov: 1M LiTFSI v TEGDME:DOL in 1M LiTFSI v TFEE:DOL. Na podlagi rezultatov smo ugotovili pomembnost strukture in lastnosti ogljikovega gostitelja pri omočljivosti, zadrževanju žvepla in končni zmogljivosti akumulatorja. S pridobljenimi podatki lahko bolje razumemo, kako lahko z ustrezno izbiro materialov izboljšamo delovanje Li–S akumulatorjev.

Language:Slovenian
Keywords:litij-žveplov akumulator, turbostratični flash grafen, etrski elektroliti, porozni ogljiki, karakterizacija katod
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-171649 This link opens in a new window
COBISS.SI-ID:249611523 This link opens in a new window
Publication date in RUL:29.08.2025
Views:687
Downloads:220
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Secondary language

Language:English
Title:Development of advanced electrochemical systems with turbostratic "Flash" graphene as an additive to increase the efficiency of Li-S batteries in ether electrolytes
Abstract:
Due to their high specific theoretical energy density, lithium-sulfur batteries are one of the promising candidates for energy storage in the future. However, in practice, they face a number of challenges, such as poor sulfur conductivity, polysulfide solubility, dendrite formation on the anode surface, and cathode instability. As part of the thesis, we compared the performance of two carbon hosts – ENSACO mesoporous carbon and turbostratic “flash” graphene (tFG) – in composites with sulfur. The prepared samples were analyzed using scanning electron microscopy (SEM), thermogravimetric analysis (TGA), contact angle measurement to determine wettability, X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), and galvanostatic discharge and charge measurements at different current rates. The use and comparison of two different ether electrolytes also played an important role: 1M LiTFSI in TEGDME:DOL and 1M LiTFSI in TFEE:DOL. Based on the results, we determined the importance of the structure and properties of the carbon host in terms of wettability, sulfur retention, and battery performance. The obtained data allows us to better understand how the performance of Li–S batteries can be improved by selecting the appropriate materials.

Keywords:lithium–sulfur battery, turbostratic flash graphene, ether-based electrolytes, porous carbons, cathode characterization

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