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Temperaturna stabilnost in viskoelastične lastnosti silikonske gume
ID Pavlič, Gal (Author), ID Oseli, Alen (Mentor) More about this mentor... This link opens in a new window, ID Slemenik Perše, Lidija (Comentor)

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Abstract
Trajnost tesnilnih izdelkov in struktur iz silikonske gume lahko določimo na več načinov, pri čemer imajo simulacije v virtualnem svetu številne prednosti vezane na ekonomsko, časovno in energetsko učinkovitost. Za napovedovanje takšnega vedenja pa potrebujemo informacije o samem časovno-odvisnem vedenju materiala, ki je bil glavni cilj predstavljene raziskave. V sklopu aktivnosti je bilo tako potrebno opredeliti termično stabilnost materiala, napetostno mejo linearne viskoelasičnosti in nazadnje potrebno materialno funkcijo. Omenjene analize so bile izvedene z uporabo diferenčnega dinamičnega kalorimetra (DSC) in modularnega rotacijskega reometra v strižnem načinu obremenjevanja. Ugotovili smo, da ima silikonska guma temperaturo steklastega prehoda pri T$_g$ = -60°C, kot tudi to, da se začne proces dodatnega zamreževanja nad temperaturo 150°C. Testi za določitev strižne materialne funkcije J (t) so bili izvedeni znotraj LVO, t.j. pri τ$_{LVE}$ = 0,0172 MPa, in uporabo časovno temperaturne superpozicije (t-Ts). Izkaže se, da dano temperaturno območje, t.j. od 25°C do 150°C, omogoča časovno odvisni popis materialne funkcije J(t) skozi 6 dekad, kjer je sprememba vrednosti funkcije izrazito majhna, od 0,66 1/MPa do 0,83 1/MPa (ekvivaletno spremembi modula od 1,5MPa do 1,2 MPa).

Language:Slovenian
Keywords:silikonska guma, termične lastnosti, viskoelastične lastnosti, termo-mehanska stabilnost, časovno odvisno vedenje
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FS - Faculty of Mechanical Engineering
Year:2025
Number of pages:XI, 34 f.
PID:20.500.12556/RUL-170635 This link opens in a new window
UDC:536:544.236.4:678.7(043.2)
COBISS.SI-ID:244735491 This link opens in a new window
Publication date in RUL:11.07.2025
Views:180
Downloads:40
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Secondary language

Language:English
Title:Thermal stability and viscoelastic properties of Silicon rubber
Abstract:
The sustainability of sealing products and structures made from silicone rubber can be determined in several ways, with simulations in the virtual reality offering numerous advantages related to economic, time, and energy efficiency. However, predicting such behavior requires information about the time-dependent behavior of the material, which was the primary objective of the presented research. Within the scope of activities, it was necessary to define the thermal stability of the material, the stress limit of linear viscoelasticity (LVO), and, finally, the required material function. The mentioned analyses were conducted using a differential dynamic calorimeter and a modular rotational rheometer in shear loading mode. We found that silicone rubber has a glass transition temperature at T$_g$ = -60°C and that the process of additional crosslinking begins above a temperature of 150°C. Tests to determine the shear material function J(t) were carried out within the LVO range, i.e., under τ$_{LVE}$ = 0.0172 MPa, using time-temperature superposition (t-Ts). It was shown that the given temperature range, i.e., from 25°C to 150°C, enables the time-dependent characterization of the material function J(t) through six decades, where the change in the function's value is remarkably small, from 0.66 1/MPa to 0.83 1/MPa (equivalent to a modulus change from 1.5 MPa to 1.2 MPa).

Keywords:silicone rubber, thermal properties, viscoelastic properties, thermo-mechanical stability, time-dependent behavior

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