Assessing silicate catchment dynamics of the Oplotnica River (Slovenia) through stable carbon and nitrogen isotopes

Kanduč, Tjaša (author), Vrabec, Mirijam (author), Verbovšek, Timotej (author), McIntosh, Jennifer (author), Žlindra, Daniel (author), Vilhar, Urša (author)

This study investigated the sources of carbon and nitrogen in a small, silicate-dominated catchment (Oplotnica River, Pohorje, Slovenia) with two creeks, Lukanjski and Javorski, from 2012 to 2014. Additionally, carbon and nitrogen cycling in soil profiles was studied at Javorski Creek. Isotopic analyses of river water, particulates, and sediments provided a more holistic view of the sources of carbon and nitrogen, weathering contributions, and the evasion or sequestration of CO$_2$ in the atmosphere within the catchments. The weathering of rocks, such as granodiorite and quartz diorite, influences water geochemistry. The Oplotnica River and its tributaries were characterized by the ion composition: Na$^+$ > Ca$^{2+}$ > Mg$^{2+}$ > K$^+$ and HCO$_3$$^−$ > SO$_4$$^{2−}$ > Cl$^−$ > NO$_3$$^−$. Partial pressure of CO$_2$ concentrations in river and creeks ranged from 1.1 to 13.4 times that of atmospheric pressure, representing a source of CO$_2$ to the atmosphere. The carbon isotope value of dissolved inorganic carbon (δ$^{13}$C$_{DIC}$) ranged from −9.8 to −1.4‰ in river, while in the creeks, it ranged from −26.1 to −4.7‰, reflecting the degradation of organic matter and exchange with the atmosphere. The intensity of bicarbonate weathering for the Oplotnica River at its gauging station was 10.4 mmol/(l⋅km$^2$⋅s), characteristic of silicate watersheds. The isotopic composition of carbon (δ$^{13}$C) and nitrogen (δ$^{15}$N) in river sediments reflects values typical of soil and temperate (C3) plants. This study is significant on both local and global levels, as it addresses the contribution of weathering rates and the release of CO$_2$ to the atmosphere from small silicate watersheds.

• Language: English
• Keywords: river systems, silicate catchment, water–soil interactions, stable isotopes, weathering intensity, Oplotnica River
• Work type: Article
• Typology: 1.01 - Original Scientific Article
• Organization: NTF - Faculty of Natural Sciences and Engineering
• Publication status: Published
• Publication version: Version of Record
• Year: 2025
• Number of pages: 33 str.
• Numbering: Vol. 31, iss. 1, art. 5
• PID: 20.500.12556/RUL-168897
• UDC: 502/504
• ISSN on article: 1573-1421
• DOI: 10.1007/s10498-025-09439-w
• COBISS.SI-ID: 234492675
• Publication date in RUL: 06.05.2025

Record is a part of a journal

• Title: Aquatic geochemistry
• Shortened title: Aquat. geochem.
• Publisher: Springer Nature
• ISSN: 1573-1421
• COBISS.SI-ID: 513122585

Licences

• License: CC BY 4.0, Creative Commons Attribution 4.0 International
• Link: http://creativecommons.org/licenses/by/4.0/
• Description: This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

• Language: Slovenian
• Keywords: reke, sistemi, izotopi