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Proizvodnja polimlečne kisline iz organskih odpadkov
ID Homar, Sebastjan (Author), ID Žnidaršič Plazl, Polona (Mentor) More about this mentor... This link opens in a new window

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Abstract
Onesnaževanje s plastiko je ena največjih okoljskih težav današnjega časa, zato se pojavlja večja potreba po proizvodnji biorazgradljivih polimerov, med katerimi je tudi polimlečna kislina. Namen diplomske naloge je pregledati raznolike možnosti pridobivanja mlečne kisline iz biomase 2. generacije (odpadki industrije in kmetijstva) ter njene polimerizacije v polimlečno kislino skozi vse štiri korake (predobdelava surovin, fermentacija, čiščenje mlečne kisline, polimerizacija). Predobdelava substrata je ključnega pomena za omogočanje lažje saharifikacije, predvsem pri lignoceluloznih odpadkih. Fermentacija poteka z bakterijami ali glivami pri čemer se parametri procesa (pH, temperatura, zračenje, inhibitorji) razlikujejo glede na organizem in substrat. Pri čiščenju mlečne kisline se uporabljajo različne tehnike, kot sta kristalizacija z nakisanjem in reaktivna ekstrakcija. Postopek čiščenja poteka v več korakih, kar ima za posledico manjše izkoristke ekstrakcije. Polimerizacija mlečne kisline poteka z direktno polimerizacijo, azeotropno dehidracijo ali metodo odpiranja laktidnega obroča, pri čemer slednja daje najkakovostnejši polimer, a je energetsko najzahtevnejša. Prihodnji razvoj proizvodnje polimlečne kisline teži k izboljšanju izkoristka procesa čiščenja mlečne kisline ter uporabe organizmov (naravnih ali gensko spremenjenih), ki bi imeli manjšo potrebo po hranilih, možnost homofermentativne uporabe tako heksoz kot pentoz in večjo odpornost na ostre industrijske pogoje (visoka temperatura, nizek pH, inhibitorji). To bi naredilo proizvodnjo polimlečne kisline bolj ekonomsko konkurenčno in trajnostno naravnano.

Language:Slovenian
Keywords:mlečna kislina, predobdelava surovin, pogoji fermentacije, čiščenje mlečne kisline, polimerizacija
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-168884 This link opens in a new window
COBISS.SI-ID:235379203 This link opens in a new window
Publication date in RUL:05.05.2025
Views:284
Downloads:80
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Secondary language

Language:English
Title:Polylactic acid production from organic wastes
Abstract:
Plastic pollution is one of the biggest environmental problems of our time, which is why there is a growing need for the production of biodegradable polymers, including polylactic acid. The purpose of the thesis is to review the various options for obtaining lactic acid from 2nd generation biomass (industrial and agricultural waste) and its polymerization into polylactic acid through all four steps (raw material pretreatment, fermentation, lactic acid purification, polymerization). Substrate pretreatment is of key importance for facilitating easier saccharification, especially in the case of lignocellulosic waste. Fermentation is carried out with bacteria or fungi, with process parameters (pH, temperature, aeration, inhibitors) varying depending on the organism and substrate. Various techniques are used in the purification of lactic acid, such as crystallization-acidolysis and reactive extraction. The purification process is carried out in several steps, which results in lower extraction yields. The polymerization of lactic acid is carried out by direct polymerization, azeotropic dehydration or the lactide ring-opening method, the latter of which yields the highest quality polymer but is the most energy-intensive. Future developments in polylactic acid production aim to improve the efficiency of the lactic acid purification process and the use of organisms (natural or genetically modified) that would have a lower nutrient requirement, the possibility of homofermentatively utilizing both hexoses and pentoses, and greater resistance to harsh industrial conditions (high temperature, low pH, inhibitors). This would make polylactic acid production more economically competitive and sustainable.

Keywords:lactic acid, pretreatment of raw materials, fermentation conditions, purification of lactic acid, polymerization

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