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Določanje karbonatov z različnimi analitskimi tehnikami v realnih vzorcih
ID Kavčič, Nika (Author), ID Kolar, Mitja (Mentor) More about this mentor... This link opens in a new window, ID Ducman, Vilma (Comentor)

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Abstract
Karbonati so kemijske spojine, s katerimi se srečujemo vsak dan. Najdemo jih v številnih sedimentnih kamninah, v vodi, prehranskih dopolnilih, okostjih morskih organizmov ipd. Uporabljamo jih predvsem v gradbeni in farmacevtski industriji. Zaradi njihove vsesplošne uporabnosti in pogostosti v naravi, bi bilo pomembno, da se jim nameni več pozornosti ne le pri urah geografije, temveč tudi pri pouku kemije. V ta namen je bila izdelana učna enota za osnovne oziroma srednje šole, s pomočjo katere bi učenci spoznali karbonate, njihovo uporabnost v vsakdanjem življenju, kako jih lahko določamo in zakaj moramo za določitev uporabiti več različnih analitskih metod. Kot primer materialov, ki jih sestavljajo karbonati, bi učenci v okviru učne enote spoznali naravne kamne ter pepele in žlindre. Pri slednjih dveh bi kot zanimivost spoznali tudi proces mineralne karbonatizacije, kot enega izmed procesov skladnega z načeli zelene kemije za zmanjšanje ogljičnega odtisa. Spoznali bi tudi nekaj tehnik za določanje karbonatov in sicer gravimetrijo, kalcimetrijo, termogravimetrično analizo (TGA) in rentgensko praškovno difrakcijo (XRD). Za gravimetrično določanje karbonatov je bila zasnovana tudi laboratorijska vaja, kot dodatek pa so bile v okviru magistrskega dela izvedene tudi določitve karbonatov s kalcimetrom, TGA in XRD, vendar bi v okviru učne enote te tehnike učenci spoznali le v teoriji, kot načine s katerimi določamo karbonate v analitskih laboratorijih.

Language:Slovenian
Keywords:karbonati, gravimetrija, termogravimetrična analiza (TGA), rentgenska praškovna difrakcija (XRD), mineralna karbonatizacija
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-168034 This link opens in a new window
COBISS.SI-ID:230604035 This link opens in a new window
Publication date in RUL:26.03.2025
Views:554
Downloads:952
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Secondary language

Language:English
Title:Determinaton of carbonates using different analytical techniques in real samples
Abstract:
Carbonates are chemical compounds that are encountered every day. They are found in numerous sedimentary rocks, in water, in food supplements, in the skeletons of marine organisms and so on. They are mainly used in construction, and pharmaceutical industry. Due to their wide distribution and occurrence in nature, it would be important to pay more attention to them not only in geography lessons, but also in chemistry lessons. To this end, a teaching unit for primary and secondary schools has been developed to help students understand carbonates, their use in everyday life, methods for their identification and the reasons why several analytical methods are required for accurate identification. As examples of materials composed of carbonates, students would examine natural rocks, ash, and slag. In relation to the latter two materials, as an interesting addition, they would also learn about the process of mineral carbonation as one of the methods of reducing the carbon footprint in the context of green chemistry. Students will also be introduced to various techniques for the determination of carbonates, including gravimetry, calcimetry, thermogravimetric analysis (TGA) and X-ray powder diffraction (XRD). A laboratory exercise is designed for the gravimetric determination of carbonates. In addition, carbonates were determined using a calcimeter, TGA and XRD as part of the master's thesis. However, these techniques will only be presented theoretically as methods used in analytical laboratories for carbonate determination as part of the teaching unit.

Keywords:carbonates, gravimetry, thermogravimetric analysis (TGA), X-ray diffraction (XRD), mineral carbonation

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