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Oksidacija modelnih komponent lignina in razvoj kinetičnih modelov
ID Ciringer, Martin (Author), ID Likozar, Blaž (Mentor) More about this mentor... This link opens in a new window

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Abstract
Lignin je najbolj razširjen vir aromatov na Zemlji. Zaradi njegove kompleksnosti se tako znanost kot industrija že desetletja trudita odkriti način, kako ga funkcionalizirati in pretvoriti v bazne kemikalije ali produkte z dodano vrednostjo. Z željo raziskati kemijo lignina, so v magistrski nalogi preučevane različne ligninske modelne komponente; vanilin, acetovanilon, katehol in resorcinol. Vzpostavljeni so bili kinetični modeli, ki popišejo odvisnost od pH vrednosti in temperature in tako dobro opišejo oksidacijo modelnih komponent v bazičnem pod milimi pogoji. Ugotovljeno je bilo, da poteka oksidacija protoniranih in deprotoniranih zvrsti različno hitro. Primerjava reaktivnosti modelnih komponent pa lahko služi kot odskočna deska za nadaljnje eksperimente funkcionalizacije lignina.

Language:Slovenian
Keywords:ligninske modelne komponente, kinetično modeliranje, oksidacija v bazičnem, lignin, oksidacija s kisikom
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2025
PID:20.500.12556/RUL-167700 This link opens in a new window
COBISS.SI-ID:229026563 This link opens in a new window
Publication date in RUL:07.03.2025
Views:492
Downloads:100
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Secondary language

Language:English
Title:Oxidation of Lignin Model Compounds and Development of Kinetic Models
Abstract:
Lignin is the most abundant source of aromatics on Earth. Due to its complex structure, science and industry have been striving for decades to discover ways to convert it into basic chemicals or to value-added products by its modification and functionalisation. To explore the chemistry of lignin, various model compounds – vanillin, acetovanillone, catechol and resorcinol – were studied in this master's thesis. Kinetic models were established to describe the dependence on pH and temperature, effectively characterizing the oxidation of the model compounds under basic mild conditions. It was found that the oxidation rates of protonated and deprotonated species differ significantly. The comparison of the reactivity of these model compounds can serve as a springboard for further experiments in lignin functionalisation.

Keywords:Lignin model compounds, kinetics modelling, oxidation in alkali, lignin, oxygen oxidation

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