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Določitev eksplozijskih parametrov in karakteristik praškastega polimernega vzorca
ID Zadravec, Tadej (Author), ID Novosel, Barbara (Mentor) More about this mentor... This link opens in a new window

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Abstract
Magistrsko delo se ukvarja z raziskovanjem nevarnosti prašnih eksplozij v procesih, kjer se uporabljajo gorljivi prahovi. Ti prahovi so običajno zelo majhni in imajo veliko specifično površino, kar omogoča hitro reakcijo z oksidantom ob prisotnosti vira vžiga. Med najbolj eksplozijsko nevarne prašne snovi sodijo: sladkor, moka, premog, lesni prah, različni polimerni materiali, guma, prahovi različnih kovin itd. Delo podrobno proučuje eksperimentalne metode za določanje ključnih parametrov, ki vplivajo na prašne eksplozije, vključno z minimalno vžigno energijo, minimalno eksplozijsko koncentracijo, maksimalnim eksplozijskim tlakom ter maksimalno hitrostjo porasta tlaka. Poleg tega je predstavljena klasifikacija prašnih eksplozij ter opis polimernih materialov, kot so polietilen visoke gostote (HDPE), polipropilen (PP) in polietilen tereftalat (PET), ki se v največjih deležih uporabljajo v proizvodnem obratu. V eksperimentalni del so bile vključene še nekatere druge metode: določanje gorljivosti, sejalna analiza, določanje nasipne in zbite gostote, analiza velikosti delcev, termična analiza ter določanje specifične površine. S temi metodami so bila pokrita vsa ključna področja karakterizacije prašnih delcev. Rezultati primerjave med vzorcema »as it is« in frakcije »<100 μm« kažejo na znatne razlike v eksplozijskih parametrih. Za vzorec »as it is« je bila izmerjena minimalna vžigna energija manj kot 3 mJ, minimalna eksplozijska koncentracija pa je bila 60 g/m3, dočim je bila MVE za vzorec »<100 μm« v območju med 3 in 10 mJ, MEK pa 30 g/ m3. Pmax je za vzorec »<100 μm« 7,9 bar, za »as it is« pa 7,4 bar. Pri (dp/dt)max pride do nekoliko večje razlike, saj le ta znaša za vzorec »<100 μm« 469 bar/s in za »as it is« 624 bar/s. Prikazani podatki nakazujejo na to, da je pri manjših delcih lažje doseči pogoje za vžig in posledično tudi prašno eksplozijo. Rezultati poudarjajo pomembnost nadzora nad velikostjo delcev pri obravnavi prašnih materialov v industrijskih obratih. Manjši delci zahtevajo strožje varnostne ukrepe saj predstavljajo večje tveganje za nastanek prašne eksplozije, medtem ko večji delci predstavljajo manjše tveganje. Pridobljeni rezultati tako prispevajo k boljšemu razumevanju vpliva velikosti delcev na eksplozijske parametre in pomaga pri oblikovanju ustreznih varnostnih protokolov za ravnanje z eksplozivnimi prašnimi delci. Med glavne ukrepe za zagotavljanje varnosti v proizvodnih obratih spadajo redno usposabljanje in ozaveščanje zaposlenih, redno čiščenje in vzdrževanje delovnih prostorov in opreme, uporaba antistatičnih oblačil in eksplozijsko varne opreme ter ozemljitev delovne opreme. Posamezni varnostni ukrepi sicer povečajo varnost, vendar se najboljše rezultate doseže, če se uvede različne varnostne ukrepe, ki se med seboj prepletajo in kot celota zagotavljajo maksimalno protieksplozijsko varnost.

Language:Slovenian
Keywords:prašne eksplozije, eksplozijski parametri, polietilen visoke gostote (HDPE), polipropilen (PP), polietilen tereftalat (PET)
Work type:Master's thesis/paper
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2024
PID:20.500.12556/RUL-164444 This link opens in a new window
Publication date in RUL:25.10.2024
Views:54
Downloads:114
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Secondary language

Language:English
Title:Determination of explosion parameters and polymer dust sample characteristics
Abstract:
This master's thesis explores the dangers of dust explosions in processes involving combustible powders. These powders are usually very small and have a large specific surface area, which enables them to react rapidly with the oxidant when an ignition source is present. The most explosive dust substances include sugar, flour, coal, wood dust, various polymer materials, rubber, various metal powders, etc. The thesis closely examines experimental methods for determining key parameters which influence dust explosions: minimum ignition energy, minimum explosible concentration, maximum explosion pressure and maximum pressure rise rate. Furthermore, it introduces a classification of dust explosions and a description of polymer materials such as high-density polyethylene (HDPE), polypropylene (PP) and polyethylene terephthalate (PET), which are most commonly used in industrial plants. Several other methods are included in the experimental part: determination of flammability, sieve analysis, determination of bulk and compaction density, analysis of particle size, thermal analysis and determination of specific surface area. These methods encompass all the key areas of dust particle characterization. The results of the comparison between the “as it is” sample and the “<100 μm” fraction show significant differences in explosion parameters. The minimum ignition energy of the “as it is” sample was measured to be less than 3 mJ, and the minimum explosible concentration was 60 g/m3, whereas the MIE of the “<100 μm” sample was in the range between 3 and 10 mJ, and the MEC was 30 g/m3. Pmax is 7.9 bar for the “<100 μm” sample and 7.4 bar for the “as it is” sample. There is a slightly larger difference in (dp/dt)max as this only amounts to 469 bar/s for the “<100 μm” sample and 624 bar/s for the “as it is” sample. The data indicates that it is easier to achieve conditions for ignition and a consequent dust explosion with smaller particles. These results highlight the importance of particle size control when dealing with dusty materials in industrial plants. While larger particles pose a lower risk, smaller particles pose a greater risk of dust explosions and thus require stricter safety measures. The obtained results thus contribute to a better understanding of the influence particle size has on explosion parameters and help with designing appropriate safety protocols for handling explosive dust particles. The most important measures to ensure safety in industrial plants include regular employee training and awareness raising, regular cleaning and maintenance of work spaces and equipment, the use of antistatic clothing and explosion-proof equipment, and the grounding of work equipment. While individual safety measures increase safety to some extent, the best results are achieved with the simultaneous use of a number of different measures which, working as a whole, ensure maximum explosion safety.

Keywords:dust explosions, explosion parameters, high-density polyethylene (HDPE), polypropylene (PP), polyethylene terephthalate (PET)

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