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Razvoj metode za opredeljevanje nukleacijskega potenciala in livarskih tehnoloških lastnosti Al zlitin : doktorska disertacija
ID Žbontar, Matic (Author), ID Mrvar, Primož (Mentor) More about this mentor... This link opens in a new window

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Abstract
V okviru doktorske disertacije smo z namenom vpliva nečistoč na metalurško kvaliteto taline obravnavali zlitino AlMg6Si2MnZr. Za omenjeno zlitino je bila izdelana baza podatkov za virtualen izračun livarskih procesov. Z v ta namen izdelano merilno celico za enostavno termično analizo so bile za različno pripravljene taline na osnovi osnovnega materiala izmerjene ohlajevalne krivulje, ki so bile natančno okarakterizirane za pridobitev karakterističnih temperatur s področja strjevanja ter oceno sproščenih latentnih toplot. Taline oz. serije posameznih vzorcev so se razlikovale po načinih priprave in poskusov vmešanja oksidnih delcev (Al2O3). Merilna celica je bila za zagotavljanje natančne opredelitve mase vzorca nameščena na tehtnico. Poleg enostavne termične analize so bile vzporedno v drugi celici izvedene tudi meritve električne upornosti med strjevanjem in nadaljnjim ohlajanjem. Vpogled v mikrostrukturo vseh vzorcev je bil izveden s pomočjo svetlobne in elektronske mikroskopije. Zaradi kompleksne strukture materiala na mikro nivoju so bile za natančnejšo opredelitev tako osnovnega materiala kot tudi izpeljank izvedeni termodinamski izračuni glede na podatke o kemijskih sestavah posameznih serij vzorcev. Termodinamski izračuni in rezultati enostavnih termičnih analiz so bili podkrepljeni z diferenčno vrstično kalorimetrijo. Ugotovljeno je bilo, da ima ravnanje s talino obravnavanega materiala v fazi priprave velik vpliv na končno mikrostrukturo, zaradi česar proizvajalec najverjetneje tudi ozko omejuje priporočljivo temperaturno območje za uporabo, odsvetuje pretaljevanje materiala in modificiranje ter udrobnjevanje taline.

Language:Slovenian
Keywords:zlitina AlMg6Si2MnZr, enostavna termična analiza, mikrostruktura, nekovinski vključki, nukleacijski potencial
Work type:Doctoral dissertation
Typology:2.08 - Doctoral Dissertation
Organization:NTF - Faculty of Natural Sciences and Engineering
Place of publishing:Ljubljana
Publisher:M. Žbontar
Year:2024
Number of pages:XIII, 185 str.
PID:20.500.12556/RUL-163035 This link opens in a new window
UDC:669
COBISS.SI-ID:212635139 This link opens in a new window
Publication date in RUL:01.10.2024
Views:127
Downloads:39
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Secondary language

Language:English
Title:Development of method for defining nucleation potential and foundry technological properties of Al alloys : Ph. D. thesis
Abstract:
Within the scope of the doctoral dissertation, we examined the alloy AlMg6Si2MnZr to investigate the influence of impurities on the metallurgical quality of the melt. A database for numerical simulations was developed for this alloy. Using a specially designed measuring cell for simple thermal analysis, cooling curves were recorded for differently prepared melts based on the primary alloy. These curves were precisely characterized to obtain characteristic temperatures from the solidification range and to estimate the released latent heats. The melts or series of individual samples differed in preparation methods and attempts to incorporate oxide particles (Al2O3). To ensure accurate determination of the sample mass, the measuring cell was placed on a balance. In addition to simple thermal analysis, measurements of electrical resistivity during cooling were also conducted simultaneously in another cell. Insight into the microstructure of all samples was obtained through light and electron microscopy. Due to the complex micro-level structure of the material, thermodynamic calculations were performed for both the base material and derivatives based on the chemical compositions of individual series of samples to provide more precise characterization. Thermodynamic calculations and results of simple thermal analyses were complemented by differential scanning calorimetry. It was found that handling the melt of the material under study during the preparation phase has a significant impact on the final microstructure, leading the manufacturer to likely narrow down the recommended temperature range for use, discourage remelting of the material, and modification or refining of the melt.

Keywords:alloy AlMg6Si2MnZr, simple thermal analysis, microstructure, non metallic inclusions, nucleation potential

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