izpis_h1_title_alt

Stabilni izotopi svinca, cinka, stroncija in železa v pesku peskovnikov in tleh Celjske kotline : magistrsko delo
ID Hribljan, Tina (Author), ID Jarc, Simona (Mentor) More about this mentor... This link opens in a new window, ID Miler, Miloš (Comentor)

.pdfPDF - Presentation file, Download (4,64 MB)
MD5: 7F786A464919A4CF3C56231FD845BBF7

Abstract
Celje s širšo okolico je zaradi preteklih industrijskih dejavnosti obremenjeno s potencialno toksičnimi elementi (PTE). Nanje so še posebno občutljivi otroci. V preteklosti so bile že ugotovljene povišane vrednosti PTE v nekaterih peskovnikih. Na izbranih lokacijah peskovnikov v Celjski kotlini smo ponovili monitoring peska in bližnjih tal ter rezultate primerjali z rezultati starejših študij. Z izotopskimi analizami svinca, cinka, stroncija in železa smo poskušali določiti potencialne vire onesnaževanja. V peskovnikih so se deleži frakcije <0,04 mm (<1 %) in deleži frakcije 0,125–0,04 mm (<10 %) zmanjšali. Prevladuje frakcija 1–0,125 mm: med 74 % in 95 %. V dveh peskovnikih smo zaznali večjo vsebnost CaO in MgO, kar tudi kaže na jalovinski material iz Mežiške doline, ki so ga v preteklosti uporabili kot pesek za peskovnike za nasutje. V vzorcih so še vedno povečane vsebnosti PTE (predvsem As, Ba, Pb in Zn). V nekaterih peskovnikih so presežene kritične in opozorilne vrednosti za Ba, Cd, Cr, Pb in Zn, presežene so tudi mejne vrednosti za As in Mo. S pomočjo izotopskih razmerij 87Sr/86Sr, ? 66Zn, ? 68Zn, ? 56Fe in ? 57/54Fe smo ugotovili, da se na vseh obravnavanih lokacijah izotopska sestava vzorcev tal in peska delno ujema z izotopsko sestavo vzorcev jalovine iz mežiškega Pb-Zn rudnika in žlindre iz stare Cinkarne Celje. Razmerja 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 208Pb/207Pb, 207Pb/206Pb kažejo na večjo podobnost z vzorci jalovine iz Mežice. Najverjetneje je obremenjenost peskovnikov in bližnjih tal s PTE posledica kombinacije različnih virov: tako jalovine iz Mežice, žlindre iz Celja in drugih neprepoznanih virov.

Language:Slovenian
Keywords:netradicionalni stabilni izotopi, potencialno toksični elementi, izvor onesnaženja, jalovina
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:NTF - Faculty of Natural Sciences and Engineering
Place of publishing:Ljubljana
Publisher:T. Hribljan
Year:2024
Number of pages:XVI, 62 f.
PID:20.500.12556/RUL-160830-538cd7a1-90c8-7424-8dfa-10f97a180dc1 This link opens in a new window
UDC:55
COBISS.SI-ID:212064515 This link opens in a new window
Publication date in RUL:05.09.2024
Views:220
Downloads:39
Metadata:XML DC-XML DC-RDF
:
Copy citation
Share:Bookmark and Share

Secondary language

Language:English
Title:Stable isotopes of lead, zinc, strontium and iron in sandbox sands and soils of Celje basin : master's thesis
Abstract:
Celje and its wider surroundings are burdened by potentially toxic elements (PTEs) due to past industrial activities, to which children are particularly vulnerable. In the past, elevated levels of PTEs have been detected in some sandboxes. At selected sandbox sites in the Celje Basin, we repeated the monitoring of sand and nearby soils and compared the results with those of older studies. Isotopic analyses of lead, zinc, strontium and iron were carried out to identify potential sources of contamination. In the sandboxes, the fraction <0.04 mm (<1%) and the fraction 0.125-0.04 mm (<10%) decreased. The 1-0.125 mm fraction dominates: between 74 % and 95 %. Higher CaO and MgO contents were detected in two of the sandpits, also indicating that the Mežica Valley mine waste material was used in the past as gravel for the embankment sandboxes. Soil samples still contain elevated levels of PTEs (mainly As, Ba, Pb and Zn), critical and warning values for Ba, Cd, Cr, Pb and Zn are exceeded in some sandpits, and the limit values for As and Mo are also exceeded. Using the isotopic ratios 87Sr/86Sr, δ66ZnJMC, δ68Zn, δ 56Fe and δ 57/54Fe, we found that at all sites the isotopic composition of the soil and sand samples partially matched the isotopic composition of the samples of the mine waste from the Pb-Zn mine in Mežica and the slag from Celje (the old Cinkarna Celje). The 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 208Pb/207Pb, 207Pb/206Pb ratios indicate a greater similarity to the Mežica mine waste samples. It is most likely that the PTE contamination of the sandboxes and nearby soils is due to a combination of different sources: both the mine waste from Mežica, the slag from Celje and other unidentified sources.

Keywords:non traditional stable isotopes, potentially toxic elements, source of contamination, mine waste

Similar documents

Similar works from RUL:
Similar works from other Slovenian collections:

Back