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Vpliv dolgotrajnega namakanja na izpiranje bakrovih učinkovin iz impregnirane smrekovine : diplomski projekt
ID Repič, Rožle (Author), ID Humar, Miha (Mentor) More about this mentor... This link opens in a new window, ID Thaler, Nejc (Comentor), ID Pohleven, Franc (Reviewer)

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Abstract
Les je gospodarsko pomemben material, zaradi česar ga želimo zaščititi pred razkrojem. V ta namen uporabljamo tudi biocidno zaščito, to pomeni, da les impregniramo s kemikalijami, ki so strupene ali odbijajoče za glive in insekte. Baker etanolaminski pripravki so trenutno najpomembnejša skupina biocidnih proizvodov za zaščito lesa v tretjem in četrtem razredu uporabe. Poleg učinkovitosti sredstva proti škodljivcem je izpiranje aktivnih učinkovin najpomembnejši kriterij za izbiro biocidnih proizvodov. Izpiranje aktivnih učinkovin je negativna lastnost, ki zmanjšuje učinkovitost in ima negativen vpliv na okolje. Izpiranja se ne da popolnoma preprečiti, nanj pa lahko do neke mere vplivamo, če poznamo dejavnike od katerih je odvisno. Pripravili smo 900 vzorcev iz treh lesnih vrst, ki smo jih impregnirali s štirimi različnimi postopki. Impregnirane vzorce smo namočili v destilirano vodo in jih izpirali do enajst tednov. Nekatere vzorce smo izpostavili nihanju temperature. Po treh, petih, sedmih, devetih in enajstih tednih smo določili količino preostalega bakra v lesu. Tako smo dobili časovno dinamiko izpiranja. Izkazalo se je, da je izpiranje najintenzivnejše v prvih tednih, kasneje pa se upočasni. Navzem sredstva pri smrekovini se giblje med približno 100 kg/m3 pri namakanju, do približno 600 kg/m3 pri kotelskih postopkih impregnacije. Iz lesa je pa v 11 tednih izpralo 25 % - 40 % bakra, pri smrekovini približno 30 %.

Language:Slovenian
Keywords:les, zaščita lesa, bakrovi pripravki, izpiranje
Work type:Diploma project paper
Typology:2.11 - Undergraduate Thesis
Organization:BF - Biotechnical Faculty
Place of publishing:Ljubljana
Publisher:R. Repič
Year:2016
Number of pages:IX, 31 f.
PID:20.500.12556/RUL-158884 This link opens in a new window
UDC:630*84
COBISS.SI-ID:2635657 This link opens in a new window
Publication date in RUL:21.06.2024
Views:247
Downloads:36
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Secondary language

Language:English
Title:Influence of long term soaking on leaching of copper based preservatives from impregnated spruce wood : B. Sc. thesis
Abstract:
Wood is economically important material, which has to be protected if used in outdoor applications. For this purpose biocidal protection can be used, meaning that wood is impregnated with chemicals that are toxic or repellent to fungi and insects. Copper ethanolamine based preservatives are currently the most important group of preservatives for wood protection in the third and fourth use class. In addition to the effectiveness of the preservative, leaching of preservatives is the most important criterion for the selection of biocidal products. Leaching of active ingredients is a negative phenomenon, which reduces the effectiveness and has a negative impact on the environment as well. Leaching cannot be completely avoided, but it may be influenced to some extent, if we know the factors which affect leaching. We prepared 900 samples from three different wood species, and impregnated by four different procedures. Impregnated samples were soaked in distilled water and leached for eleven weeks. Some samples were also exposed to fluctuations in temperature. After three, five, seven, nine and eleven weeks, the amount of residual copper in the wood was determined. These data enabled calculation of leaching curves. It turns out that leaching is most intense during the first few weeks, but it then slows down. The uptake of preservative was from about 100 kg/m3 when dipping, to about 600 kg/m3 when deeply impregnated. Between 25 % - 40 % of copper compounds were leached out in 11 weeks, about 30 % for spruce.

Keywords:wood, wood protection, copper based preservatives, leaching

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