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Reološke lastnosti fenol-formaldehidnega lepila med procesom utrjevanja : diplomsko delo - univerzitetni študij
ID Veren, Zlatko (Author), ID Šernek, Milan (Mentor) More about this mentor... This link opens in a new window, ID Petrič, Marko (Reviewer)

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Abstract
Z oscilatornim testom smo raziskali reološke lastnosti fenol-formaldehidnih (FF) lepil med procesom utrjevanja pri konstantni frekvenci obremenjevanja 1Hz, v sistemih les-lepilo-les in aluminij-lepilo-aluminij. Raziskali smo vpliv hitrosti segrevanja (10 °C/min, 20 °C/min, 30 °C/min, 40 °C/min, 50 °C/min in 60 °C/min) in vrste podlage (aluminijasti, bukovi in smrekovi diski) na elastični strižni modul (G') in viskozni strižni modul (G'') FF lepila. Za vpliv temperature na G' in G'' FF lepila pri različnih hitrosti segrevanja smo uporabili le aluminijaste diske, saj so najbolj izkazovali karakteristične lastnosti pri utrjevanju. Raziskali smo tudi vpliv podlage na točko želiranja in zamreženja FF lepila pri različnih hitrostih segrevanja. Ugotovili smo, da sta oba modula, pri uporabi aluminijastih diskov, začela naraščati nekoliko prej, kot pri uporabi lesenih diskov, uporaba bukovih diskov v primerjavi s smrekovimi pa ni bistveno vplivala na G' in G'' FF lepila. Hitrost segrevanja FF lepila je pri vseh vrstah podlag vplivala na čas utrjevanja FF lepila, ki se je s povišano hitrostjo segrevanja zmanjševal. Pri uporabi aluminijastih diskov smo ugotovili, da se je z naraščanjem hitrosti segrevanja FF lepila, zmanjševala tudi temperatura, pri kateri sta krivulji obeh modulov začeli naraščati. Časi želiranja in zamreženja FF lepila se glede na vrsto podlage niso bistveno razlikovali. Večje razlike so nastale pri temperaturi želiranja in zamreženja FF lepila.

Language:Slovenian
Keywords:reologija, utrjevanje lepil, fenol-formaldehidna lepila, elastični strižni modul, viskozni strižni modul
Work type:Undergraduate thesis
Typology:2.11 - Undergraduate Thesis
Organization:BF - Biotechnical Faculty
Place of publishing:Ljubljana
Publisher:Z. Veren
Year:2016
Number of pages:XIV, 106 f.
PID:20.500.12556/RUL-158867 This link opens in a new window
UDC:630*8
COBISS.SI-ID:2594185 This link opens in a new window
Publication date in RUL:21.06.2024
Views:25
Downloads:1
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Secondary language

Language:English
Title:Rheological properties of phenol-formaldehyde adhesive during the process of curing : graduation thesis - university studies
Abstract:
With the oscillation test we researched rheological properties of phenol-formaldehyde (PF) adhesives during the process of curing at the constant frequency of loading 1Hz in the system wood-adhesive-wood and aluminium-adhesive-aluminium. We researched the influence of the heating rate (10°C/min, 20°C/min, 30°C/min, 40°C/min, 50°C/min in 60°C/min) and types of substrate (aluminium, beech and spruce discs) on storage modulus (G') and loss modulus (G'') of PF adhesives. For the influence of temperature on the G' and G'' of PF adhesives at different heating rate, we used only aluminium discs, since they the best showed characteristic properties during curing. We also researched the influence of the substrate on the gel point and on the point of cross-linking of PF adhesives at different heating rates. It was found out that both moduli, when we used aluminium disks, started to increase earlier, than when we used wood discs. Using the beech discs compared to the spruce ones did not influence on the G' and G'' of PF adhesives. The heating rate of the PF adhesive at all types of substrates influenced on time of curing of the adhesive, which was decreasing with the increasing heating rate. With the use of aluminium discs we found out that with the increasing heating rate of the PF adhesive, the temperature at which the curves of both moduli started to increase, was decreasing. The gel and crosslinking times of the PF adhesive did not differ, irrespective of the substrate type. Larger differences were observed at the gel and crosslinking temperatures of the PF adhesive.

Keywords:rheology, curing of adhesives, phenol-formaldehyde adhesives, storage modulus, loss modulus

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