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Rheological study of hybrid aqueous suspension of TEMPO-oxidized cellulose nanofibrils and graphene oxide
ID Malnarič, Iris (Author), ID Krajnc, Matjaž (Author), ID Šebenik, Urška (Author)

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Abstract
The incorporation of graphene oxide (GO) into a nanocellulose matrix has attracted considerable attention due to the unique advantages of both components. This study focuses on investigating the viscoelastic and flow properties of hybrid aqueous suspensions (2.00 w/v%), composed of TEMPO-oxidized cellulose nanofibrils (TOCNF) and GO at different TOCNF/GO weight ratios. To adjust the elastic properties of the hybrid suspensions, calcium ions are introduced, varying the concentration systematically to study their effects on the hybrid network structure. All blends exhibit shear-thinning behaviour and demonstrate elastic, gel-like properties. Notably, in the absence of calcium ions, the enhancement of elastic properties is more pronounced at higher GO fractions. Conversely, with the introduction of calcium ions, the enhancement of elastic properties becomes particularly important at higher TOCNF fractions. For the quantitative evaluation of these enhancements, we employ the logarithmic mixing rule. Significant positive deviations from the predictions of the logarithmic mixing rule are ascribed to the complex, concentration-dependent arrangement of cellulose nanofibrils and GO liquid crystals in the aqueous suspension, coupled with ionic crosslinking induced by calcium ions. The study aims to contribute to the understanding of the rheological behaviour of the TOCNF/GO hydrogel, showing potential advancements in various applications.

Language:English
Keywords:TEMPO-oxidized cellulose nanofibrils, graphene oxide, blending effect, calcium ions, hydrogel, rheology
Work type:Article
Typology:1.01 - Original Scientific Article
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Publication status:Published
Publication version:Version of Record
Year:2024
Number of pages:18 str.
Numbering:Vol. , iss.
PID:20.500.12556/RUL-158308 This link opens in a new window
UDC:661.728:532.135
ISSN on article:0969-0239
DOI:10.1007/s10570-024-05978-7 This link opens in a new window
COBISS.SI-ID:197573379 This link opens in a new window
Publication date in RUL:04.06.2024
Views:46
Downloads:14
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Record is a part of a journal

Title:Cellulose
Shortened title:Cellulose
Publisher:Springer
ISSN:0969-0239
COBISS.SI-ID:512098329 This link opens in a new window

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Keywords:TEMPO-oksidirana celulozna nanovlakna, grafen oksid, efekt mešanja, kalcijevi ioni, hidrogel, reologija

Projects

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P2-0191
Name:Kemijsko inženirstvo

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