Thermodynamics of the ion association of potassium cobalt(III) bis(1,2-dicarbollide) in acetonitrile, methanol and dimethyl sulfoxide

Šarac, Bojan (author), Ogrin, Peter (author), Medoš, Žiga (author), Urbič, Tomaž (author), Matějíček, Pavel (author), Bešter-Rogač, Marija (author)

The molar conductivities, Λ, of dilute solutions of potassium cobalt(III) bis(1,2-dicarbollide) (K[COSAN]) in methanol (MeOH), acetonitrile (MeCN) and dimethyl sulfoxide (DMSO) were determined at different temperature ranges. The data were analysed in the frame of Barthel’s low-concentration chemical model (lcCM) to obtain the limiting molar conductivities, Λ$^∞$, and standard association constants, K$^o_A$, of K[COSAN]. To confirm the ion association of oppositely charged ions K$^+$ and [COSAN]$^–$, molecular dynamics (MD) simulations were performed, in which the values of K$^o_A$ from the potential of the mean force between the pair of particles (ions) were determined. From temperature dependence of K$^o_A$, the thermodynamic parameters for ion association, namely standard free enthalpy ΔG$^o_A$, enthalpy ΔH$^o_A$, and entropy ΔS$^o_A$, were estimated. The dilution enthalpies of concentrated solutions of K[COSAN] in organic solvents were also determined by using isothermal titration calorimetry (ITC). Our experimental results show that K$^+$ and [COSAN]$^–$ ions form ion pairs in all the investigated solvents. Ion association is most pronounced in MeOH and MeCN and the least expressed in DMSO, the process is endothermic and is accompanied by an increase in entropy. The agreement between the calculated values of K$^o_A$ and the thermodynamic parameters obtained by conductivity and MD simulations follow the same trend.

• Language: English
• Keywords: potassium cobalt(III) bis(1, 2-dicarbollide), acetonitrile, methanol, dimethyl sulfoxide, ion association, thermodynamics
• Work type: Article
• Typology: 1.01 - Original Scientific Article
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Publication status: Published
• Publication version: Version of Record
• Year: 2023
• Number of pages: 7 str.
• Numbering: Vol. 391, pt. A, art. 123234
• PID: 20.500.12556/RUL-153058
• UDC: 544.3
• ISSN on article: 0167-7322
• DOI: 10.1016/j.molliq.2023.123234
• COBISS.SI-ID: 168557827
• Publication date in RUL: 15.12.2023

Record is a part of a journal

• Title: Journal of molecular liquids
• Shortened title: J. mol. liq.
• Publisher: Elsevier
• ISSN: 0167-7322
• COBISS.SI-ID: 15382277

Licences

• License: CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
• Link: http://creativecommons.org/licenses/by-nc-nd/4.0/
• Description: The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.

Secondary language

• Language: Slovenian
• Keywords: termodinamika, asociacija ionov, acetonitril, metanol, dimetil sulfoksid