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Določitev in izris evtektičnega faznega diagrama med amonijevim nitratom in natrijevim nitratom s pomočjo DSC analize, optimizacija priprave vzorca
ID Pirc, Sara (Author), ID Čelan Korošin, Nataša (Mentor) More about this mentor... This link opens in a new window

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Abstract
Fazni diagram grafično ponazori faze heterogenega sistema, kjer faza predstavlja homogeni del. Pri svojem diplomskem delu sem s pomočjo termogravimetrične analize (TGA) in predvsem diferenčne dinamične kalorimetrije (DSC) skonstruirala dvokomponentni fazni diagram za spojini amonijev nitrat (AN) in natrijev nitrat (NN), katerih zmes tvori evtektični sistem, ki je homogena zmes s temperaturo tališča, ki je nižja od tališč posameznih komponent. Določila sem, da je evtektična točka pri vrednostih 74,735 % AN in 25,265 % NN. Na osnovi predhodnih meritev sem skonstruirala še optimalni fazni diagram z evtektično točko pri vrednostih 73,921 % AN in 26,079 % NN.

Language:Slovenian
Keywords:evtektični fazni diagram, DSC, amonijev nitrat, natrijev nitrat
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2023
PID:20.500.12556/RUL-149132 This link opens in a new window
COBISS.SI-ID:165375491 This link opens in a new window
Publication date in RUL:04.09.2023
Views:1072
Downloads:38
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Secondary language

Language:English
Title:Determination and drawing of the eutectic phase diagram between ammonium nitrate and sodium nitrate by DSC analysis, optimisation of sample preparation
Abstract:
A phase diagram graphically illustrates the phases of a heterogeneous system, where the phase represents the homogeneous part. In my thesis I used thermogravimetric analysis (TGA) and, in particular, differential scanning calorimetry (DSC) to create a two-component phase diagram for the compounds ammonium nitrate (AN) and sodium nitrate (NN), the mixture of which forms a eutectic system, i.e. a homogeneous mixture with a melting point lower than the melting points of the individual components. I found that the eutectic point is at the values of 74.735% for AN and 25.265% for NN. Based on the preliminary measurements, an optimal phase diagram with a eutectic point at 73.921 % AN and 26.079 % NN was also constructed.

Keywords:eutectic phase diagram, DSC, ammonium nitrate, sodium nitrate

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