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Odstranjevanje potencialno strupenih kovin iz odpadnega blata iz čistilne naprave z uporabo EDTA
ID Kaurin, Anela (Author), ID Morales Arteaga, Juan Francisco (Author), ID Leštan, Domen (Author)

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Abstract
Odpadno blato iz čistilnih naprav (ČN) ima zaradi velike hranilne vrednosti potencial za uporabo v kmetijstvu, vendar je pogosto onesnaženo s potencialno strupenimi kovinami (PSK). V raziskavi smo preverili ali ReSoil® tehnologija, ki temelji na uporabi EDTA (50, 70 in 100 mmol l$^{-1}$ omogoča učinkovito odstranjevanje PSK iz odpadnega blata, vzetega po aerobni (blato1) in anaerobni (blato2) biološki obdelavi. Največji delež odstranitve Pb smo dosegli v blatu1 (do 60 %), največji delež odstranitve Zn in Cu pa v blatu2 (do 55 in 29 %). Vsebnost hranil se po remediaciji ni bistveno spremenila, le vsebnost dostopnega fosforja se je v blatu2 po remediaciji do 1,7-krat zmanjšala, vendar je še vedno ostala velika (489- 510 mg 100$^{-1}$ g$^{-1}$). Po remediaciji so bile koncentracije v izpirkih za vse kovine, razen za Zn, pod mejo za nenevarne snovi. Za dokazovanje možnosti recikliranja procesnih raztopin in EDTA smo blato2 oprali s 50 mmol l$^{-1}$ pralno raztopino v seriji 5 zaporednih remediacij in pri tem v povprečju odstranili 28 % Pb, 48 % Zn, 35 % Cu, 30 % Mn in 10 % Fe. ReSoil® tehnologija sicer omogoča odstranjevanje PSK iz blata in pri tem ohrani njegovo hranilno vrednost, vendar je učinkovitost tehnologije odvisna od postopkov obdelave blata na ČN.

Language:Slovenian
Keywords:EDTA, potencialno strupene kovine, remediacija, odpadno blato, čistilne naprave, aerobna biološka obdelava, anaerobna biološka obdelava
Work type:Article
Typology:1.01 - Original Scientific Article
Organization:BF - Biotechnical Faculty
Publication status:Published
Publication version:Version of Record
Year:2022
Number of pages:14 str.
Numbering:Vol. 118, No. 4
PID:20.500.12556/RUL-143704 This link opens in a new window
UDC:631
ISSN on article:1854-1941
DOI:10.14720/aas.2022.118.4.2705 This link opens in a new window
COBISS.SI-ID:136861443 This link opens in a new window
Publication date in RUL:09.01.2023
Views:789
Downloads:177
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Record is a part of a journal

Title:Acta agriculturae Slovenica
Publisher:Biotehniška fakulteta, Oddelek za agronomijo in Oddelek za zootehniko, Biotehniška fakulteta, Oddelek za agronomijo in Oddelek za zootehniko, Univerza v Ljubljani, Biotehniška fakulteta, Založba Univerze v Ljubljani
ISSN:1854-1941
COBISS.SI-ID:219581184 This link opens in a new window

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:English
Title:Removal of potentially toxic metals from sewage sludge using EDTA
Abstract:
Sewage sludge has the potential to be used as a fertilizer in agriculture because of its high nutritional value, but it is often contaminated with toxic metals (TM). This study investigated whether ReSoil® technology, based on the use of EDTA (50, 70, and 100 mmol l$^{-1}$), efficiently removes TM from sewage sludge collected after aerobic (blato1) and anaerobic (blato2) treatment. The highest removal efficiency of Pb was achieved in blato1 (up to 60 %) and of Zn and Cu in blato2 (up to 55 and 29 %, respectively). The content of nutrients did not change significantly after remediation, only available phosphorus decreased up to 1.7-times in blato2, but its content remained high (489-510 mg 100$^{-1}$ g$^{-1}$). After remediation, the concentration of all metals, except Zn, in the leachates was below the limit for non-hazardous substances. To demonstrate the possibility of recycling process solutions and EDTA, blato2 was washed in 5 consecutive batches with 50 mmol l$^{-1}$ washing solution, removing on average 28 % Pb, 48 % Zn, 35 % Cu, 30 % Mn, and 10 % Fe. ReSoil® technology removes metals from sludge and preserves its nutritional value. However, the efficiency of the technology depends on the treatment process used in the wastewater treatment plant.

Keywords:EDTA, toxic metals, remediation, sewage sludge, wastewater treatment plants, aerobic biological treatment, anaerobic biological treatment

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