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Tetrahydrated bis(monoaqua-bis(ethylenediamine)copper(II))-diaqua-bis(ethylenediamine)copper(II) dicitrate : preparation, crystal structure, Raman and FTIR spectra and paramagnetic behavior
ID
Vakulka, Andrii
(
Author
),
ID
Goreshnik, Evgeny A.
(
Author
),
ID
Jagodič, Marko
(
Author
),
ID
Jagličić, Zvonko
(
Author
),
ID
Trontelj, Zvonko
(
Author
)
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https://www.tandfonline.com/doi/full/10.1080/00958972.2022.2126314
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Abstract
The crystals of the first copper(II) ethylenediamine complex containing citrate anion have been prepared and characterized. Despite the archetypical character of the copper(II) ethylenediamine complexes, some structural peculiarities were found to be interesting since they are quite rare even among the mentioned type of the complex compounds i.e. a presence of both mono and diaqua-bis(ethylenediamine)copper(II) cations together in the same crystal structure, intramolecular hydrogen bonding of the citric anion, cis,trans-configuration of the citric anion and the disordered C-C bond of the ethylenediamine molecule in the monoaquabis(ethylenediamine)copper(II) cation, which in fact is a co-existence of two energetically close dd and dk conformers. The Raman as well as FTIR spectra were recorded and discussed. Finally, the magnetic measurements have shown paramagnetic behavior of the prepared complex in a wide range of temperatures.
Language:
English
Keywords:
copper(II) complex
,
ethylenediamine complex
,
copper(II) citrate
,
crystal structure
,
Raman spectrum
,
FTIR spectrum
Work type:
Article
Typology:
1.01 - Original Scientific Article
Organization:
FS - Faculty of Mechanical Engineering
FGG - Faculty of Civil and Geodetic Engineering
Publication status:
Published
Publication version:
Version of Record
Year:
2022
Number of pages:
Str. 2062-2076
Numbering:
Vol. 75, no. 15/16
PID:
20.500.12556/RUL-143691
UDC:
548/549
ISSN on article:
1029-0389
DOI:
10.1080/00958972.2022.2126314
COBISS.SI-ID:
123517699
Publication date in RUL:
09.01.2023
Views:
755
Downloads:
71
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Record is a part of a journal
Title:
Journal of coordination chemistry
Shortened title:
J. coord. chem.
Publisher:
Taylor & Francis
ISSN:
1029-0389
COBISS.SI-ID:
515741465
Licences
License:
CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Link:
http://creativecommons.org/licenses/by-nc-nd/4.0/
Description:
The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.
Projects
Funder:
ARRS - Slovenian Research Agency
Project number:
P1-0045
Name:
Anorganska kemija in tehnologija
Funder:
ARRS - Slovenian Research Agency
Project number:
P2-0348
Name:
Nove slikovno-analitske metode
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