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Reološke lastnosti polimernih kompozitov pri različnih koncentracijah okroglih steklenih delcev
ID Ručigaj, Janez (Author), ID Slemenik Perše, Lidija (Mentor) More about this mentor... This link opens in a new window

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Abstract
Uporaba polimernih materialov je v industriji vse bolj pogosta. Polimeri imajo veliko dobrih lastnosti, kot so enostavnost uporabe in majhna specifična teža, kljub vsemu pa njihovo področje uporabe omejujejo lastnosti, kot sta slaba trdnost in togost. Ena izmed rešitev, kako lahko negativne lastnosti izboljšamo oz. obidemo, so kompoziti. S pravilno kombinacijo dveh ali več komponent lahko celo dosežemo magnetnost in električno prevodnost polimernih materialov. Vedno bolj narašča uporaba visokokoncentriranih kompozitov, ki so ponavadi sestavljeni iz polimerne matrice in polnila. Njihova uporaba ima velik potencial, vendar se pri njih določene lastnosti, kot je reološko vedenje, popolnoma spremenijo. Da bi njihove lastnosti bolje razumeli, smo na kompozitu steklenih kroglic v matrici polipropilena izvedli amplitudne frekvenčne in reološke meritve. Eksperimentalne rezultate smo primerjali s teoretičnimi izračuni relativne viskoznosti. Ugotovili smo, da se viskoznost proučevanega kompozita veča z večanjem deleža polnila, newtonski plato pa se pomika k nižjim vrednostim strižne napetosti. S frekvenčnimi testi smo ugotovili, da so vzorci z večjim deležem polnila manj odvisni od viskoznega dela in vedno bolj odvisni od elastičnega dela materiala. Na vzorcih z večjimi deleži polnila smo opazili zlomljene delce stekla. Pri analiziranih vzorcih smo ugotovili, da ne moremo z enim modelom opisati celega koncentracijskega območja, lahko pa pri točno določenem območju določimo model, ki tisto koncentracijo najbolje opiše.

Language:Slovenian
Keywords:kompoziti, visokokoncentrirani, polipropilen, steklene kroglice, viskoznost
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FS - Faculty of Mechanical Engineering
Place of publishing:Ljubljana
Publisher:[J. Ručigaj]
Year:2022
Number of pages:XXI, 52 str.
PID:20.500.12556/RUL-135254 This link opens in a new window
UDC:678.061:543.318.3(043.2)
COBISS.SI-ID:100048643 This link opens in a new window
Publication date in RUL:03.03.2022
Views:1071
Downloads:55
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Secondary language

Language:English
Title:Rheological properties of polymer composites at different concentrations of glass spherical particles
Abstract:
Polymers are becoming more common. They have many positive properties such as ease of use and low specific weight, but negative properties such as poorer strength and rigidity limit their areas of application. One of the solutions where the negative properties can be improved are composites. With a combination of two or more components, we can even achieve the magnetism and electrical conductivity of polymers. There is a growing use of highly-filled composites, which usually consist of a polymer matrix and a filler. Their use has great potential, but rheological behavior can be different than that of primary polymer. To better understand this behavior, amplitude, frequency and viscosity measurements were performed on a composite of glass beads in a polypropylene matrix. The test results were then compared with theoretical calculations of relative viscosity. We found that the viscosity of the composite increases with increasing filler concentration and the Newtonian plateau shifts to lower shear stress values. Through frequency tests, we found that samples with higher filler concentration behave less depending on the viscous part and more on the elastic part of the material. Broken glass particles were observed on samples with larger filler concentrations. We came to the conclusion that we can not describe the whole concentration range with one model, however we can determine which model best describes defined concentration.

Keywords:composites, highly-filled, polypropylene, glass beads, viscosity

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