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Napake pri merjenjih z ionoselektivnimi elektrodami
ID Ogrin, Žiga (Author), ID Cerar, Janez (Mentor) More about this mentor... This link opens in a new window

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Abstract
V diplomskem delu opisujem sestavne dele iono-selektivnih elektrod in napake, ki se lahko pojavijo pri merjenjih z ionoselektivnimi elektrodami. S pomočjo znanstvenih člankov in literature s področja ionoselektivnih elektrod sem proučeval, kako lahko na neželen odziv instrumenta vplivajo vzorci, ki vsebujejo interferenčne ione ali imajo ekstremne pH-vrednosti. Prikazano je, kakšnim merilom mora ustrezati elektrolitski ključ in kakšen pomen ima le-ta pri odkrivanju merskih napak. Dodatno sem raziskal na kaj moramo biti pozorni pri delu z biološkimi vzorci, zakaj se pojavlja lezenje elektrodnega signala in kako pravilno shranjevati elektrode ter jim na ta način podaljševati življenjsko dobo. Poudarjen je bil tudi pomen previdnosti pri pripravi standardnih raztopin in pozornosti pri uporabi primernega merilnika napetosti. Za vsako izmed opisanih interferenc so bile raziskane in predlagane primerne rešitve.

Language:Slovenian
Keywords:membrana, indikatorska elektroda, elektrolitski ključ
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2021
PID:20.500.12556/RUL-131722 This link opens in a new window
COBISS.SI-ID:87491587 This link opens in a new window
Publication date in RUL:01.10.2021
Views:1209
Downloads:84
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Secondary language

Language:English
Title:Errors in Measurements with Ion-Selective Electrodes
Abstract:
In this work, potential sources of errors when analyzing samples with Ion-Selective Electrodes have been studied. With the help of scientific articles and literature on Ion-Selective Electrodes, it was shown how samples containing interfering ions and/or having extreme pH values can affect the measured values. It was also shown how important is the adequate choice of a salt bridge and how crucial this choice is when systematic errors in measurements need to be identified. It was investigated what should be considered when dealing with biological samples, what is the source of electrode drift and how a proper electrode storage can ensure a long shelf life. Carefulness is emphasized when preparing standard solutions as well as when an adequate measuring instrument has to be chosen. For chosen interferences the procedures helping minimize measurement errors have been investigated and proposed.

Keywords:Membrane, Indicator Electrode, Salt Bridge

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