Organokovinski kompleksi kovin prehoda z acetilenskimi ligandi

Kladnik, Špela (author), Gazvoda, Martin (mentor)

Kovinski acetilidi pogosto nastopajo kot katalizatorji ali reakcijski intermediati v sinteznih postopkih. Med kovinami, ki se uporabljajo v povezavi s kovinskimi acetilidi, prevladujejo baker, srebro, zlato in tudi železo. V kombinaciji z omenjenimi kovinami je bilo do sedaj za pripravo tovrstnih organokovinskih kompleksov uporabljenih že veliko različnih ligandov. V sklopu diplomskega dela smo uspešno sintetizirali bakrov in srebrov fenilacetilid. Poleg tega smo pripravili tudi organokovinske acetilide na osnovi bakra in zlata z različnimi izbranimi ligandi: tj. 1,2-bis(difenilfosfino)etanom (DPPE), fenantrolinom in imidazolijevo soljo.

• Language: Slovenian
• Keywords: kovinski acetilidi, organokovinski kompleksi, acetilenski ligandi, prehodne kovine
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2021
• PID: 20.500.12556/RUL-129948
• COBISS.SI-ID: 82734595
• Publication date in RUL: 09.09.2021

KLADNIK, Špela, 2021, Organokovinski kompleksi kovin prehoda z acetilenskimi ligandi [online]. Bachelor’s thesis. [Accessed 2 June 2025]. Retrieved from: https://repozitorij.uni-lj.si/IzpisGradiva.php?lang=eng&id=129948

Secondary language

• Language: English
• Title: Organometallic transition metal acetylene complexes

Abstract

Metal acetylides often serve as catalysts or reaction intermediates in synthetic processes. Among the metals used in combination with acetylene ligand, copper, silver, gold and iron predominate. In combination with these metals, many different ligands have been used for synthesis of these organometallic acetylide complexes. In this thesis, we have successfully synthesized copper and silver phenylacetylides. In addition, we have also prepared organometallic acetylides based on copper and gold with various selected ligands: e.g., 1,2-bis(diphenylphosphino)ethane (DPPE), phenanthroline and imidazole salt.

• Keywords: metal acetylides, organometallic complexes, acetylene ligands, transition metals