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Organokovinski kompleksi kovin prehoda z acetilenskimi ligandi
ID Kladnik, Špela (Author), ID Gazvoda, Martin (Mentor) More about this mentor... This link opens in a new window

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Abstract
Kovinski acetilidi pogosto nastopajo kot katalizatorji ali reakcijski intermediati v sinteznih postopkih. Med kovinami, ki se uporabljajo v povezavi s kovinskimi acetilidi, prevladujejo baker, srebro, zlato in tudi železo. V kombinaciji z omenjenimi kovinami je bilo do sedaj za pripravo tovrstnih organokovinskih kompleksov uporabljenih že veliko različnih ligandov. V sklopu diplomskega dela smo uspešno sintetizirali bakrov in srebrov fenilacetilid. Poleg tega smo pripravili tudi organokovinske acetilide na osnovi bakra in zlata z različnimi izbranimi ligandi: tj. 1,2-bis(difenilfosfino)etanom (DPPE), fenantrolinom in imidazolijevo soljo.

Language:Slovenian
Keywords:kovinski acetilidi, organokovinski kompleksi, acetilenski ligandi, prehodne kovine
Work type:Bachelor thesis/paper (mb11)
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2021
PID:20.500.12556/RUL-129948 This link opens in a new window
COBISS.SI-ID:82734595 This link opens in a new window
Publication date in RUL:09.09.2021
Views:355
Downloads:77
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Secondary language

Language:English
Title:Organometallic transition metal acetylene complexes
Abstract:
Metal acetylides often serve as catalysts or reaction intermediates in synthetic processes. Among the metals used in combination with acetylene ligand, copper, silver, gold and iron predominate. In combination with these metals, many different ligands have been used for synthesis of these organometallic acetylide complexes. In this thesis, we have successfully synthesized copper and silver phenylacetylides. In addition, we have also prepared organometallic acetylides based on copper and gold with various selected ligands: e.g., 1,2-bis(diphenylphosphino)ethane (DPPE), phenanthroline and imidazole salt.

Keywords:metal acetylides, organometallic complexes, acetylene ligands, transition metals

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