Sinteza novih triazolidinov in njihovih srebrovih(I) koordinacijskih spojin

Črnilogar, Tjaša (author), Kljun, Jakob (mentor)

Namen diplomske naloge je bil pripraviti nove spojine, narediti karakterizacijo sintetiziranih produktov, preučiti potencialno aplikacijo snovi in predlagati nove sintezne postopke. V okviru diplomskega dela sem preučila sintezne postopke za triazolidine in naredila tri nove ligande, ki sem jih okarakterizirala z jedrsko magnetno resonanco (NMR) in masno spektrometrijo (HRMS). Raziskala sem potencialno aplikacijo triazolidinov in srebrovih kompleksov, zapisala lastnosti srebrovih soli in opisala sinteze 1:1 srebrovih kompleksov. V sklepnem poglavju sem predlagala sintezne postopke za 1:1 komplekse s srebrom in sintetiziranim ligandom.

• Language: Slovenian
• Keywords: srebro, 1, 2, 4-triazolidin-3-tion, srebrovi kompleksi
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2021
• PID: 20.500.12556/RUL-129737
• COBISS.SI-ID: 79398147
• Publication date in RUL: 07.09.2021

Secondary language

• Language: English
• Title: Synthesis of new triazolidines and their silver(I) coordination compounds

Abstract

The purpose of my thesis was to prepare and characterize new compounds, to study their potential use and suggest new synthesis protocols. As part of a thesis the known synthetic protocols for triazolidines are described and three new compounds were synthesized. The new compounds were characterized by NMR analysis and mass spectrometry. The potential use of triazolidines and silver complexes, the properties of silver complexes and the synthetic protocols of 1:1 silver complexes are described. The synthesis of 1:1 complexes with silver and synthesised ligand are proposed.

• Keywords: silver, 1, 2, 4-triazolidne-3-thione, silver complex