Uporaba plastovitih dvojnih hidroksidov za čiščenje vode

Zidar, Ana (author), Cerc Korošec, Romana (mentor)

Namen mojega diplomskega dela je bil pregledati možnosti uporabe glinenih materialov, katerih površina je pozitivno ali negativno nabita, za reševanje določenih okoljskih težav. Načrtovan je bil tudi eksperimentalni del, kjer bi najprej pripravila cink-kromov plastoviti dvojni hidroksid v obliki tanke plasti na stekleni podlagi, nato pa preverila njegovo adsorpcijsko učinkovitost za vezavo določenega barvila. Vendar pa zaradi okoliščin, povezanih z epidemijo, tega eksperimentalnega dela nisem uspela izvesti, zato sem se osredotočila na teoretični del diplomske naloge. V njem sem opisala nekaj aktualnih okoljskih težav in možne postopke reševanja le-teh z uporabo glin, katerih površina ima pozitivni ali negativni naboj. Glede na naboj površine gline delimo na kationske in anionske. Posledica površinskega naboja je sposobnost vezave ionov z nasprotnim nabojem iz okolice (vode ali prsti) na trdno površino glin. Prav ta lastnost je uporabna na primer pri proizvodnji nove oblike gnojil, pri čiščenju odplak iz živinorejskih obratov, pri preprečevanju cvetenja vode z odstranjevanjem fosfatih ionov iz vode, pri čiščenju arzenatnih ionov iz pitne vode ter barvil iz odpadnih vod tekstilne industrijie. Plastoviti dvojni hidroksidi pa imajo še eno uporabno lastnost, so namreč fotokatalitsko aktivni in lahko katalizirajo razpad nekaterih organskih molekul, na primer azo barvil, ki se uporabljajo v tekstilni industriji. Analiznih tehnik, uporabnih za raziskave na omenjejem področju, je veliko. UV-Vis spektroskopija je uporabna za preiskovanje adsorpcijske in fotokatalitske učinkovitosti plastovitih dvojnih hidroksidov. Z rentgensko praškovno difrakcijo potrjujemo nastalo fazo po sintezi materiala in preiskujemo spremembe v strukturi plastovitih dvojnih hidroksidov pri toplotni obdelavi in rehidraciji. Znano je namreč, da imajo plastoviti dvojni hidroksidi t.im. spominski efekt; po toplotni obdelavi se plastovita struktura poruši, po rehidrataciji pa se lahko rekonstruira. Pri vzorcih, segretih na zelo visoko temperaturo, pa se prvotna struktura po rehidrataciji ne obnovi popolnoma.

• Language: Slovenian
• Keywords: plastoviti dvojni hidroksidi (LDH), hidrotalcit, plastoviti dvojni oksidi (LDO), adsorpcija, okolju škodljivi ioni
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2021
• PID: 20.500.12556/RUL-128322
• COBISS.SI-ID: 74020099
• Publication date in RUL: 08.07.2021

Secondary language

• Language: English
• Title: Application of layered double hydroxides for water treatment

Abstract

The aim of my thesis was to seek the possibility of using clays with positively or negatively charged surfaces to solve certain environmental problems. An experimental part of the thesis was planned, in which I wanted to prepare a zinc-chromium double hydroxide deposited on a glass surface in the form of a thin layer, and further check its adsorption efficiency for binding a certain dye. Due to circumstances connected with epidemic situation, I was not able to do the experimental work, so I focused on the theoretical part of my diploma work. Some current environmental problems and the possible methods to solve them with charged clays are described. Charged clays are classified as cationic or anionic depending on the charge of the clay layers. The charged surface results in their ability to bind ions with opposite charge from the environment (water or soil) to their solid surface. This is useful, for example, in the development of a novel fertilizer or in the purification of sewage from livestock operations, in the prevention of algal blooms in freshwater by removing phosphate ions from the water, in the treatment of arsenic-containing drinking water, and in the removal of dyes from textile industry wastewater. Layered double hydroxides have another useful ability, they are photocatalytically active and can catalyze the decomposition of some organic molecules, such as textile azo dyes. There are many analytical methods that are useful for research in the mentioned field. UV-Vis spectroscopy is useful for studying adsorption and photocatalytic efficiency of charged clays. X-ray diffraction is used to confirm the phase obtained after the synthesis of the material, and the changes in the structure after thermal treatment and rehydration. It is known that layered double hydroxides have a so-called memory effect, which means that the layered structure collapses after thermal treatment but rebuilds after rehydration. Thermal treatment at very high temperatures prevents the complete reconstruction of the layer structure after rehydration.

• Keywords: layered double hydroxides (LDH), hydrotalcite, layered double oxides (LDO), adsorption, environmentally harmful ions