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Adenin kot kation v heksafluoridosilikatnih soleh
ID Brulc, Rok (Author), ID Pevec, Andrej (Mentor) More about this mentor... This link opens in a new window

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Abstract
V diplomskem delu opisujem sintezo heksafluoridosilikatne soli s formulo [RH2]2+[SiF6]2- (1), v kateri je R adenin. Pri sintezi so bili kot reaktanti uporabljeni: SiO2, fluorovodikova kislina in adenin. Reakcija je bila izvedena v stehiometričnem razmerju 1 : 1 med SiO2 in adeninom, kar je vodilo do nastanka dvoprotoniranega adeninskega kationa. Iz raztopine fluorovodikove kisline so se izločili kristali, ki so bili nato analizirani z rentgensko strukturno analizo. Nastali produkt sem strukturno primerjal s spojino [RH]2+[SiF6]2- (R = adenin) (2) z že znano strukturo, ki vsebuje enoprotoniran adeninski kation.

Language:Slovenian
Keywords:Adenin, heksafluoridosilikati, rentgenska strukturna analiza
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2020
PID:20.500.12556/RUL-119535 This link opens in a new window
COBISS.SI-ID:28379139 This link opens in a new window
Publication date in RUL:09.09.2020
Views:2287
Downloads:283
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BRULC, Rok, 2020, Adenin kot kation v heksafluoridosilikatnih soleh [online]. Bachelor’s thesis. [Accessed 26 July 2025]. Retrieved from: https://repozitorij.uni-lj.si/IzpisGradiva.php?lang=eng&id=119535
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Secondary language

Language:English
Title:Adenine as cation in hexafluoridosilicate
Abstract:
In this thesis I describe the synthesis of hexafluoridosilicate salt with formula [RH2]2+[SiF6]2-(1), where R is adenine. SiO2, hydrofluoric acid and adenine were used as reactants in the synthesis. The reaction was performed in a stoichiometric ratio of 1 : 1 between SiO2 and adenine, which led to the formation of a double-protonated adenine cation. Crystals were formed in hydrofluoric acid solution, which were then analyzed by X–ray crystallography. The structure of resulting product was compared with compound [RH]2+[SiF6]2- (R = adenine) (2) with known structure containing a monoprotonated adenine cation.

Keywords:Adenine, hexafluoridosilicates, X-ray crystallography

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