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Kemijski in mehanski vidik utrjevanja urea-formaldehidnega lepila : diplomski projekt
ID Jeraj, Miha (Author), ID Šernek, Milan (Mentor) More about this mentor... This link opens in a new window, ID Poljanšek, Ida (Reviewer)

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MD5: E04A0D8B31DA973B39E55AA23553B9CF
PID: 20.500.12556/rul/5047c80f-b104-4e7a-ac27-c9643c6b85d6

Abstract
Proučevali smo vpliv deleža katalizatorja in hitrost segrevanja na proces utrjevanja lepila, točneje na točko želiranja ter elastični strižni modul G'. Uporabili smo sintetično, polikondenzacijsko urea-formaldehidno lepilo (UF) tipa Prefere 10F102 s fizikalno-kemičnim načinom utrjevanja. Meritve smo izvedli z reometrom z oscilatorno metodo 2 vzporednih plošč ter diferenčno dinamično kalorimetrijo (DSC). Namen testiranja je bil iskanje morebitnih korelacij med rezultati obeh metod. Pri izvedbi eksperimenta z reometrom smo uporabili hitrosti segrevanja 5, 10 in 20 K/min in deleže katalizatorja 0,5 %,1 % , 2 % in 3 %. Kot katalizator smo uporabili 25 % vodno raztopino amonijevega sulfata. Temperaturni obseg testiranja pri reometru je bil od 30 do 95 °C, pri metodi DSC pa od 30 do 100 °C. Za določanje točke želiranja smo uporabili kriterij sečišča elastičnega strižnega modula G' in viskoznostnega strižnega modula G". Ugotovili smo, da z naraščanjem koncentracije utrjevalca in hitrosti segrevanja padata temperatura in čas točke želiranja UF lepila. Dokazali smo tudi, da so končne vrednosti modula G' približno enake ne glede na količino katalizatorja ali hitrost segrevanja. Z DSC "Model Free Kinetics" smo simulirali potrebne čase utrjevanja za doseganje določene stopnje utrjenosti UF lepila pri izbranih temperaturah.

Language:Slovenian
Keywords:urea-formaldehid, reometer, DSC, točka želiranja
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:BF - Biotechnical Faculty
Place of publishing:Ljubljana
Publisher:[M. Jeraj]
Year:2012
Number of pages:X, 41 f.
PID:20.500.12556/RUL-677 This link opens in a new window
UDC:630*824.8
COBISS.SI-ID:2046345 This link opens in a new window
Publication date in RUL:11.07.2014
Views:2308
Downloads:281
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Secondary language

Language:English
Title:Chemical and mechanical aspects of curing of urea-formaldehyde adhesive : B. Sc. thesis
Abstract:
We studied the influence of the share of catalysts and heating rate on the curing process of an adhesive, specifically the gelling point and elastic shear modulus G'. Synthetic polymeric condensation adhesive Urea-formaldehyde (UF)-type Prefere 10F102 with physical and chemical way of curing was used. Measurements were performed with rheometer having 2 parallel plates and also by differential scanning calorimetrics (DSC). The purpose of the testing was to search possible correlations between the results of both methods. We used heating rate of 5, 10 and 20 K/min and fixtures shares of 0.5 %, 1 %, 2 % and 3 % with the rheometer. As a fixture agent we used 25 % aqueous solution of ammonium sulphate. The temperature rate testing with rheometer was from 30 up to 95 °C, we used temperature rate from 30 to 100 °C for DSC. To determine the gelling point we took the intersection of the elastic shear modulus G' and the viscosity shear modulus Gʼʼ. We found that by increasing the both, the concentration of fixtures and heating rate, diminishes the temperature and speeds the time of gelling point. We have shown that the final value of the module G' are about the same, regardless the amount of catalyst or heating rate. Using the DSC "Module Free kinetics" we simulated and determined the necessary time and temperature needed to achieve a certain level of hardness.

Keywords:urea-formaldehyde, rheometer, DSC, gelling point

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