Impact of fiber diameter and surface substituents on the mechanical and flow properties of sonicated cellulose dispersions

Kopač, Tilen (author), Ručigaj, Aleš (author)

This study investigates how sonication amplitude and time affect 2 wt% cationic nanofibrils (CCNF) and microfibrils (CCMF) dispersions, focusing on mechanical properties and flow behavior. Sonication reduces fiber diameter and increases the concentration of substituent groups available for hydrogen bonding. This effect becomes significant when diameters fall below 100 nm, leading to enhanced storage and loss moduli. CCNF achieves a maximum shear modulus of 600 Pa, whereas CCMF fibers do not undergo similar size reductions. CCNF's viscosity and critical stress follow a square root relationship with sonication amplitude, due to minimal fiber size reduction at high sonication levels (smaller than 20 nm), unlike CCMF (diameter reduction up to 50 nm), which exhibits a linear increase due to more pronounced fiber fragmentation. At high sonication levels, CCNF shows an exponential rise in critical stress (up to 800 Pa), suggesting tiny fibers infiltrate the hydrogel network, thereby improving its integrity and resistance to shear stresses. By integrating theoretical models with experimental findings, this work presents a unified view of sonication's essential role in fine-tuning the mechanical and flow properties of cellulose-based materials. This research enhances understanding of cellulose dispersion behavior under sonication and provides a foundation for designing optimized cellulose-based materials.

• Language: English
• Keywords: cationic cellulose, fiber size, sonication, rheology, hydrogen interactions
• Work type: Article
• Typology: 1.01 - Original Scientific Article
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Publication status: Published
• Publication version: Version of Record
• Year: 2024
• Number of pages: 10 str.
• Numbering: Vol. , art. 136210
• PID: 20.500.12556/RUL-164261
• UDC: 661.728
• ISSN on article: 0141-8130
• DOI: 10.1016/j.ijbiomac.2024.136210
• COBISS.SI-ID: 211934723
• Publication date in RUL: 18.10.2024

Record is a part of a journal

• Title: International journal of biological macromolecules
• Shortened title: Int. j. biol. macromol.
• Publisher: Elsevier
• ISSN: 0141-8130
• COBISS.SI-ID: 25637888

Licences

• License: CC BY 4.0, Creative Commons Attribution 4.0 International
• Link: http://creativecommons.org/licenses/by/4.0/
• Description: This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

• Language: Slovenian
• Keywords: kationska celuloza, velikost vlaken, sonikacija, reologija, vodikove interakcije

Projects

• Funder: ARIS - Slovenian Research and Innovation Agency
• Project number: P2-0191
• Name: Kemijsko inženirstvo